KINETICS OF ION TRANSFER ACROSS LIQUID/LIQUID INTERFACE BY CHRONOPOTENTIOMETRY WITH LINEAR CURRENT SCANNING

被引:0
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作者
庞志诚
汪尔康
张正
机构
[1] Changchun Institute of Applied Chemistry
[2] University of Texas at E1 Paso
[3] Laboratory of Electroanalytical Chemistry
[4] Academia Sinica
[5] Changchun 130022
[6] PRC
[7] U. S. A.
基金
中国国家自然科学基金;
关键词
liquid/liquid interface; linear current scanning; ion transfer kinetics;
D O I
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中图分类号
学科分类号
摘要
The equation of the potential-current curve for the ion transfer across the liquid/liquid interface during the linear current scanning has been derived theoretically. A method to calculate the kinetics parameters for the ion transfer by the way of linear current scanning is presented. The transfer of TPAsions, which is a typical basic electrolyte ion usually used in liquld/liquid interface electrochemistry, was practically investigated at the water/nitrobenzene interface.
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页码:1172 / 1180
页数:9
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