SYNTHESIS AND CHARACTERIZATION OF A NOVEL POLYMER ELECTROLYTE BASED ON ACRYLONITRILE/N-[4-(AMINOSULFONYL)PHENYL]ACRYLAMIDE COPOLYMERS

被引：0

作者：

Ang-ran Wang ^{[1
]}

包永忠 ^{[1
]}

机构：

[1] State Key Laboratory of Chemical Engineering,Zhejiang University

来源：

Chinese Journal of Polymer Science | 2010年 / 28卷 / 01期

关键词：

Acrylonitrile; N-[4-(aminosulfonyl)phenyl]acrylamide; Copolymerization; Composition; Polymer electrolyte;

D O I：

暂无

中图分类号：

O631.3 [高聚物的化学性质];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Acrylonitrile/N-[4-(aminosulfonyl)phenyl]acrylamide(AN/ASPAA) copolymers were synthesized and used as a host of lithium ion conducting electrolytes.The composition,molecular weight and molecular weight distribution of AN/ASPAA copolymers were determined,and the influence of copolymer composition on the glass temperature of AN/ASPAA copolymers and the ion conductivity of electrolytes were investigated.The molecular weights of AN/ASPAA copolymers were lower than those of AN and ASPAA homopolymers due to the cross-termination reaction.The glass temperatures of AN/ASPAA copolymers increased as the molar fraction of ASPAA units in copolymers increased.The lithium ion conductivities of the polymer electrolytes increased initially as the molar fraction of ASPAA units in copolymers increased,and a maximum conductivity was achieved when the molar fraction of ASPAA in the copolymer was 16.8%.

引用

页码：129 / 135

页数：7

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