Enhanced Pervaporative Separation of Thiophene/n-Heptane Using Metal Loaded PEBAX/PAN Membranes

被引:0
|
作者
Han Jianjian [1 ,2 ]
Wang Yidong [3 ]
Hu Yongjie [2 ]
Liu Kun [1 ]
Muhammad Yaseen [1 ,4 ]
Hu Minzhuan [2 ]
机构
[1] School of Chemistry and Chemical Engineering, Guangxi University
[2] Guangdong Testing Institute of Product Quality Supervision
[3] Guangzhou College of Commerce
[4] Institute of Chemical Sciences, University of Peshawar
关键词
transitional metal ion; facilitated mass transfer of thiophene; polyether block amide membrane; pervaporation; desulfurization;
D O I
暂无
中图分类号
TE624.55 []; TQ028.8 [新型分离法];
学科分类号
081701 ; 081702 ; 081704 ;
摘要
The mass transfer of thiophene through pervaporation(PV) membranes could be facilitated by certain transitional metal ions like Ag+, Mn2+, and Cr3+ thanks to their p complexation with thiophene. In this study, Ag~+, Mn2+, and Cr3+ions were loaded onto the polyether block amide(PEBAX)/PAN composite membranes and were tested on the performance for separation of thiophene/n-heptane mixture. Pervaporation test results showed that the pervaporative separation index increased significantly to 73.1%, 75.5%, and 97.2% at 30 oC for the Ag~+-, Mn2+-, Cr3+-loaded PEBAX membranes, respectively,as compared to the pristine PEBAX/PAN composite membrane.
引用
收藏
页码:36 / 45
页数:10
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