Electrochemical synthesis of selenocyanated imidazo[1,5-a]quinolines under metal catalyst-and chemical oxidant-free conditions

被引：6

作者：

Jinjin Zhang ^{[1
]}

Huiqiao Wang ^{[1
]}

Yaru Chen ^{[1
]}

Haiquan Xie ^{[1
]}

Chenghua Ding ^{[1
]}

Jiajing Tan ^{[2
]}

Kun Xu ^{[1
,3
]}

机构：

[1] College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University

[2] Department of Organic Chemistry, Faculty of Chemistry, Beijing University of Chemical Technology

[3] College of Life Science & Bioengineering, Beijing University of Technology

来源：

Chinese Chemical Letters | 2020年 / 31卷 / 06期

基金：

中央高校基本科研业务费专项资金资助; 北京市自然科学基金; 中国国家自然科学基金; 河南省教育厅基金;

关键词：

Electrosynthesis; Organic electrochemistry; Anodic oxidation; Imidazo[1,5-a]quinoline; Selenocyanation;

D O I：

暂无

中图分类号：

O626 [杂环化合物];

学科分类号：

070303 ; 081704 ;

摘要：

Reported herein is the first example of electrochemical selenocyanation of imidazo[1,5-a]quinolines with KSeCN under metal catalyst-and chemical oxidant-free conditions.This sustainable strategy shows a broad scope and great compatibility with functional groups,and affords synthetically and biologically important selenocyanated imidazo[1,5-a]quinolines in good to excellent yields with cheap graphite and Ni plates as the electrodes.The gram-scale synthesis was also successfully conducted,which might demonstrate the potential value of this electrochemical protocol.

引用

页码：1576 / 1579

页数：4

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