Synthesis and Structure of a Novel 3-Fold Interpenetrating Three-dimensional Coordination Polymer:[Ni(Hbyip2-)（bix）0.5（H2O）]n

被引：1
|
作者：
魏林恒 [1 ]
王子梁 [2 ]
李明雪 [2 ]
王敬平 [2 ]
机构：
[1] Institute of Natural Resources and Environmental Science,College of Environment and Planning,Henan University
[2] College of Chemistry and Chemical Engineering,Henan University
来源：
结构化学 | 2011年 / 30卷 / 04期
关键词：
crystal structure; coordination polymer; carboxylate; interpenetration; transition metal;
D O I：
10.14102/j.cnki.0254-5861.2011.04.006
中图分类号：
O634 [元素有机聚合物];
学科分类号：
摘要：
A three-dimensional coordination polymer,[Ni(Hbyip2-)(bix)0.5(H2O)]n,has been hydrothermally synthesized.Each Ni2+ ion is five-coordinated by three carboxylate O atoms from three different 5-(benzoic acid-4-yldiazenyl)isophthalate(Hbyip2-) anions,one N atom from one 1,4-bis(imidazol-1-ylmethyl)benzene(bix) ligand and one O atom from an aqua ligand displaying a distorted square-pyramid.Each Ni atom is defined by three Hbyip2-anions and each Hbyip2-anion adopts a tris(mono-dentate) ligand coordinating to three Ni2+ ions affording a 36-membered inorganic ring.These rings are further arranged into an undulated two-dimensional layer parallel to the(101) plane.Adjacent two-dimensional networks are linked by bix ligands into a three-dimensional {63,83}{63} framework with a large channel(ca.26.3 × 13.6) along the [100] direction.Each individual {63,83}{63} network interpenetrates with two others in a parallel fashion to generate a 3-fold interpenetrating network.
引用
收藏
页码：486 / 491
页数：6
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