Syntheses and Characterizations of Cyanido-bridged Dinuclear Ru-complexes and Their MMCT Properties in the One-electron Oxidation State

被引：0

作者：

刘洋 ^{[1
,2
,3
]}

朱晓权 ^{[2
]}

吴新涛 ^{[2
]}

盛天录 ^{[2
]}

机构：

[1] College of Chemistry,Fuzhou University

[2] State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

[3] University of Chinese Academy of Sciences

来源：

Chinese Journal of Structural Chemistry | 2021年 / 40卷 / 10期

基金：

美国国家科学基金会;

关键词：

D O I：

10.14102/j.cnki.0254-5861.2011-3147

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

We have designed and synthesized a family of dinuclear cyanido-bridged complexes[PY5Me2Ru(μ-CN)Ru(dppe)CpMen][PF6]2(PY5Me2=2,6-bis (1,1-bis(2-pyridyl)ethyl) pyridine,Cp=cyclopentadienyl,n=0,2[PF6]2;n=1,3[PF6]2;n=5,4[PF6]2) by using a mononuclear complex[PY5Me2Ru(μ-CN)][PF6](1) as the precursor.All the three complexes have been fully characterized by including single-crystal X-ray diffraction analysis.The one-electron oxidation complexes 23+,33+and 43+obtained in situ all show a MMCT absorption band in the visible range.The MMCT energy increases as the redox potential of the N-terminal fragments decreases,and the redox potential decreases as the number of methyl groups on the cyclopentadiene of the cyanido-nitrogen coordinated Ru metal increases,supported by the TDF/TDDFT calculations.

引用

页码：1253 / 1264

页数：12