Hydrothermal Synthesis and Crystal Structure of a Cadmium(Ⅱ) Polymer with a Two-dimensional Network Structure: [Cd(pzdc)(2,2'-bipy)]n·nH2O

被引：0
|
作者：
李秀梅 [1 ]
牛艳玲 [1 ]
刘博 [2 ]
王庆伟 [2 ]
周实 [2 ]
潘北诚 [3 ]
机构：
[1] Department of Chemistry, Tonghua Teachers College
[2] Department of Chemistry, Jilin Normal University
[3] Department of Physics, Jilin Normal University
来源：
Chinese Journal of Structural Chemistry | 2009年 / 28卷 / 01期
关键词：
coordination polymer; hydrothermal synthesis; crystal structure; luminescence;
D O I：
10.14102/j.cnki.0254-5861.2009.01.012
中图分类号：
O634 [元素有机聚合物];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A metal-organic coordination compound formulated as [Cd(pzdc)(2,2’-bipy)]n·nH2O 1 (H2pzdc = pyrazine-2,3-dicarboxylic acid, 2,2’-bipy = 2,2’-bipyridine) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P21/c with a = 10.8081(13), b = 14.4328(17), c = 10.2530(12) , β = 98.504(2)o, V = 1581.8(3) 3, C16H14CdN4O5, Mr = 454.71, Dc = 1.909 g/cm3, μ(MoKα) = 1.420 mm-1, F(000) = 904, Z = 4, the final R = 0.0230 and wR = 0.0554 for 2901 observed reflections (I > 2σ(I)). It exhibits an interesting two-dimensional network structure and shows yellow photoluminescent property at room temperature.
引用
收藏
页码：29 / 32
页数：4
相关论文
共 50 条
  • [41] Hydrothermal Synthesis, Crystal Structure and Electrochemical Properties of the Complex Cu（o-Methylbenzoic acid）2（2,2′-bipy）·（H2O）
    HE Xiao-Meia LI Chang-Honga YANG Ying-Qunb LI Weib② a (Department of Chemical Engineering
    Chinese Journal of Structural Chemistry, 2007, (02) : 206 - 210
  • [42] Hydrothermal synthesis, crystal structure and electrochemical properties of the complex Cu(o-methylbenzoic acid)2(2,2′-bipy)•(H2O)
    He Xiao-Mei
    Li Chang-Hong
    Yang Ying-Qun
    Li Wei
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (02) : 206 - 210
  • [43] Synthesis and Structure of a New Coordination Polymer [Cd(pzdc)(bpy)]n (H2pzdc = Pyrazine-2,3-dicarboxylic Acid, bpy = 2,2′-Bipyridine)
    Yi Ma
    Yong-Ke He
    Li-Tian Zhang
    Jing-Qun Gao
    Zheng-Bo Han
    Journal of Chemical Crystallography, 2008, 38 : 267 - 271
  • [44] Synthesis and crystal structure of [CuL(4, 4′-bipy) (2, 2′-bipy)H2O]ncoordination polymer
    Hu, Xing-Liang
    Zhong, Xin-Xian
    Zhao, Zhi-Yuan
    Jiang, Yi-Min
    Rengong Jingti Xuebao/Journal of Synthetic Crystals, 2009, 38 (04): : 1042 - 1045
  • [45] Synthesis, Crystal Structure and Luminescent Property of [CdCl(HL)(dpp)(H2O)]n•nH2O
    Geng Xiao-Hong
    Feng Yun-Long
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (02) : 360 - 364
  • [46] Synthesis and structure of one-dimensional cadmium coordination polymer [Cd(μ-DPIA)2(H2O)]n
    Gao, S
    Huo, LH
    Lu, ZZ
    Zhao, H
    Zhao, JG
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (08) : 1242 - 1244
  • [47] Hydrothermal synthesis and crystal structure of an one-dimensional mixed-valence molybdenum oxide [Mo3O8(2,2′-bipy)2]
    Lu, Y
    Wang, EB
    Yuan, M
    Li, YG
    Hu, CW
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 649 (1-2) : 191 - 195
  • [48] Hydrothermal Synthesis, Crystal Structure and-Photoluminescence of a New Two-Dimensional Cadmium(II) Complex [Cd3(HBTA)2(BIPA)3]n
    Liu Guang-Xiang
    Xu Yu-Yong
    Ren Xiao-Ming
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (10) : 1885 - 1889
  • [49] Synthesis and Crystal Structure of a Cadmium(Ⅱ) Coordination Polymer:[Cd2Cl4(bpme)]n·n(2H2O)
    李超柱
    黄学仁
    陈艳辉
    李家明
    蒋毅民
    结构化学, 2011, 30 (05) : 644 - 647
  • [50] Hydrothermal synthesis and crystal structure of an inclusion compound [Mn(2,2′-bipy)(H2O)4]•(m-phth)
    Deng, YF
    Kuang, DZ
    Chen, MS
    Feng, YL
    Kuang, YF
    Peng, YL
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (03) : 551 - 554
12345