A New Kinetic Method of Processing TA Data

被引:0
|
作者
张建军
任宁
机构
[1] Experimental Center
[2] Hebei Normal University
[3] Shijiazhuang
[4] Hebei 050016
[5] China
关键词
new method; thermal analysis; kinetics; the function of conversion; activation energy;
D O I
暂无
中图分类号
O643.1 [化学动力学];
学科分类号
摘要
A new method of investigating the kinetic parameters and mechanism functions of a solid phase reaction is pre-sented. This method is to analyze the data based on the use of these data at the same temperature and the same de-gree of conversion on a series of TA curves with different heating rates, so that the kinetic tripletthe activation energy E, the pre-exponential factor A and the analytical form of the function of conversion f(a) can be obtained. The main advantage of this method is that the values of E and f(a) are obtained respectively, and the determination of f(a) is not under the influence of the value of E and the calculation of the value of E is not influenced by the f(a) either.
引用
收藏
页码:1459 / 1462 +1390
页数:5
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