Two-dimensional Network Crown Ether Complex. Synthesis and Crystal Structure of 18-Crown-6 Complex: [K（18-C-6）]2[Cd-（mnt）2]

被引：2
|
作者：
王大奇
于清江
窦建民
机构：
来源：
Chinese Journal of Chemistry | 2002年 / 02期
关键词：
two dimensional network; crown ether complex; 18; crown; 6; crystal structure;
D O I：
暂无
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
The novel complex [K(18 C 6)] 2[Cd(mnt) 2] [18 C 6=18 crown 6, mnt=1,2 dicyanoethene 1,2 dithiolate, C 2S 2 (CN) 2 2 ] was synthesized and characterized by elemental analysis, IR spectrum and X ray diffraction analysis. The complex displays two dimensional network structure of [K(18 C 6)] complex segments and [Cd(mnt) 2] complex segment bridged by S K S, S K N and N K N interactions between adjacent [K(18 C 6)] and [Cd(mnt) 2] units.
引用
收藏
页码：191 / 193 +116
页数：4
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