Synthesis and Crystal Structure of Bis-(2,2' bipyridyl)-2-pyrimidinethiolate-Ni(Ⅱ) Complex

被引：0
|
作者：
CHEN Yan-Dan ZHANG Li-Yi CHEN Zhong-Ning② (State Key Laboratory of Structural Chemistry
机构：
来源：
Chinese Journal of Structural Chemistry | 2003年 / 02期
关键词：
nickel; bipyridine; pyrimidine-2-thiolate; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2003.02.012
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction between [Mn(bpy)2(MeOH)2](SbF6)2 (bpy = 2,2-bipyridine) and (Et4N)[Ni(pymt)3] (pymt = pyrimidine-2-thiolate) gave the complex [Ni(bpy)2(pymt)](SbF6) which was determined by X-ray single-crystal diffraction. The structure is of monoclinic with space group C2/c, a = 25.190(2), b = 11.3178(7), c = 19.296(1) ? b = 101.364(1)? V = 5393.4(6) 3, Mr = 718.98, Dc = 1.771 g/cm3, F(000) = 2840, m = 1.845 mm-1 and Z = 8. The final refinement gave R = 0.0641 and wR = 0.1399 for 3598 observed reflections (I > 2s(I)). The nickel(Ⅱ) atom is coordinated by four N donors from two bpy in the cis-conformation and two other atoms of S and N from one pymt, forming a distorted coordination octahedron.
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页码：179 / 181
页数：3
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