Studies on Inorganic Ion Exchanger Containing Phosphorus(IX)——Kinetics of Ion Exchange Reaction for Alkaline Earths on SVPP

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Xia Jinlan
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Inorganic ion exchanger; Stannic Vanadopyrophosphate; Kinetics of ion exchange reaction; Alkaline earths;
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A shell reaction mechanism and its mathematic model were used to inquire into the kinetics of ion exchange reaction between alkaline earth metal ions and H- form of micro-crystalline SVPP.The activation energy ( Ea ), entropy of activation ( ΔS) and self-diffusion coefficient ( Do ) of alkaline earths were calculated bysolving the Nernst-Planck equations on a IBM-PC computer. The linear relations between the bare ionic radii of alkaline earths ro andEa, ΔSor lgDo have been obtained.
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页码:84 / 89
页数:6
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