(a-Diimine)palladium catalyzed ethylene polymerization and (co)polymerization with polar comonomers

被引：0
|
作者：
Lihua Guo [1 ,2 ]
Changle Chen [3 ,4 ]
机构：
[1] State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University
[2] School of Chemistry and Chemical Engineering, Qufu Normal University
[3] Key Laboratory of Soft Matter Chemistry, Chinese Academy of Sciences
[4] Department of Polymer Science and Engineering,University of Science and Technology of China
来源：
Science China(Chemistry) | 2015年 / 58卷 / 11期
基金：
中央高校基本科研业务费专项资金资助; 中国国家自然科学基金;
关键词：
palladium; -diimine; ethylene polymerization; polar comonomer;
D O I：
暂无
中图分类号：
O631.5 [聚合反应、缩聚反应];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In this review, a recent development of cationic ?-diimine palladium(II) complexes for ethylene polymerization and copolymerization with polar functionalized comonomers was briefly described. First, the polymerization mechanism for this type of catalysts was discussed. Next, recent advances in ligand design were provided with special focus on the influence of ligand structures on the catalytic polymerization properties. Last, the ethylene homopolymerization and copolymerization with various polar comonomers, especially acrylate and vinyl ethers were summarized.
引用
收藏
页码：1663 / 1673
页数：11
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