Synthesis and Structure of a Zinc（II） Complex:[Zn（Pybta）·Cl2]n

被引：0
|
作者：
黄美华
王艰
刘平
机构：
[1] Beijing 100039
[2] Graduate School of the Chinese Academy of Sciences
[3] Fuzhou
[4] Fujian 350002
[5] Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences
[6] China
来源：
Chinese Journal of Structural Chemistry | 2008年 / 06期
关键词：
crystal structure; zigzag chain structure; multiple; π-π; interactions;
D O I：
10.14102/j.cnki.0254-5861.2008.06.007
中图分类号：
O627.23 [锌族金属有机化合物];
学科分类号：
070303 ; 081704 ;
摘要：
The title compound, [Zn(Pybta)Cl2]n (Pybta = 1-(2-pyridylmethyl)benzontriazole), has a zigzag chain structure. It crystallizes in the monoclinic system, space group P21/c with a = 9.0103(11), b = 17.0276(18), c = 9.2288(11) , β = 101.309(6)o, Mr = 346.51, V = 1388.4(3) 3, Z = 4, Dc = 1.658 g/cm3, F(000) = 696, μ = 2.143 mm1, the final R = 0.0492 and wR = 0.1236 for 2545 observed reflections with I > 2σ(I). The Zn atom is four-coordinated by two N and two Cl atoms, forming a slightly distorted tetrahedral geometry. Each zigzag chain links its adjacent symmetry- related equivalents via multiple π-π interactions, which are not frequently observed in the previously reported architectures.
引用
收藏
页码：659 / 662
页数：4
相关论文
共 50 条
  • [41] Synthesis and structure of bis(dibutyldithiocarbamate)zinc(II):: Zn2[(n-BU)2NCSS]4
    Zhang, WG
    Zhong, Y
    Tan, MY
    Tang, N
    Yu, KB
    MOLECULES, 2003, 8 (05): : 411 - 417
  • [42] The synthesis and structure of a neutral tetranuclear zinc(II) complex [Zn4(L)4][LH2=N,N-bis(2-mercaptoethyl)benzylamine]
    Spencer, DJE
    Blake, AJ
    Parsons, S
    Schröder, M
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (07): : 1041 - 1042
  • [43] Kinetics of hematite chlorination with Cl2 and Cl2 + O2. Part II. Chlorination with Cl2 + O2
    Kanari, N.
    Mishra, D.
    Filippov, L.
    Diot, F.
    Mochon, J.
    Allain, E.
    THERMOCHIMICA ACTA, 2010, 506 (1-2) : 34 - 40
  • [44] Synthesis and crystal structure of a trinuclear Zn(II) complex
    Ling-Yan, Kong
    Yong-Qing, Huang
    Xi-Hong, Lu
    Guang-Xiang, Liu
    Wei-Yin, Sun
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (08) : 1484 - 1486
  • [45] Synthesis and structure of zinc iodide complex with thiocarbamide, [Zn(CH4N2S)2I2]
    Albov, D. V.
    Buravlev, E. A.
    Savinkina, E. V.
    Zamilatskov, I. A.
    CRYSTALLOGRAPHY REPORTS, 2013, 58 (01) : 65 - 67
  • [46] Synthesis and structure of zinc iodide complex with thiocarbamide, [Zn(CH4N2S)2I2]
    D. V. Albov
    E. A. Buravlev
    E. V. Savinkina
    I. A. Zamilatskov
    Crystallography Reports, 2013, 58 : 65 - 67
  • [47] Synthesis, crystal structure of Zn(II) complex of 2-acetylthiazole N-phenyl-3-thiosemicarbazone
    Kleopatra, Ruddock
    Venkatraman, Ramaiyer
    Dasary, Samuel S. R.
    Arslan, Zikri
    Holder, Alvin A.
    Fronczek, Frank R.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [48] Synthesis and Molecular Structure of the Zinc(II) Complex Bearing an N, S Donor Ligand
    Haribabu, J.
    Priyarega, S.
    Bhuvanesh, N. S. P.
    Karvembu, R.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 61 (01) : 66 - 72
  • [49] Synthesis and crystal structure of a one-dimensional chain complex {Pd[PhS(CH2)5SPh]Cl2}n
    Xie, YB
    Li, JR
    Zheng, Y
    Bu, XH
    Zhang, RH
    JOURNAL OF MOLECULAR STRUCTURE, 2003, 645 (2-3) : 227 - 230
  • [50] Synthesis and Molecular Structure of the Zinc(II) Complex Bearing an N, S Donor Ligand
    J. Haribabu
    S. Priyarega
    N. S. P. Bhuvanesh
    R. Karvembu
    Journal of Structural Chemistry, 2020, 61 : 66 - 72
12345