Synthesis,characterization,photophysical and electrochemical properties of oxygen bridged twisted heptatomic biphenyl substituted perylene diimides

被引：0
|
作者：
Jian-Min Wang [1 ]
En-Fang He [1 ]
Hai-Long Wang [1 ]
Wen-Long Hou [1 ]
Jing Xu [1 ]
Lan Yu [1 ]
Le-Le Zhao [1 ]
Zhen-Lin Zhang [1 ]
Hai-Quan Zhang [1 ]
机构：
[1] State Key Laboratory of Metastable Materials Science and Technology, Yanshan University
来源：
Chinese Chemical Letters | 2017年 / 28卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Perylene diimide derivatives; Twisted biphenyl; Photophysical properties; Intermolecular aggregation; The energy level;
D O I：
暂无
中图分类号：
TQ610.1 [基础理论];
学科分类号：
0817 ;
摘要：
The perylene diimide derivatives(s-THBPDI and d-THBPDI) bearing oxygen bridged twisty heptatomic biphenyl in the bay positions of the perylene core through acetylene bond were designed and synthesized.The photophysical properties of the functionalized dyes were investigated in solution and solid state by UV-vis and photoluminescence(PL) spectra.Their UV-vis and PL spectrum both exhibited the different concentration-dependent behaviors due to the difference of chemical structure.Moreover,cyclic voltammetry results indicated that the introduction of oxygen bridged twisted heptatomic biphenyl could decrease the LUMO energy level of the perylene diimide effectively and made it promising material in photoelectric devices.
引用
收藏
页码：383 / 387
页数：5
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