SYNTHESIS AND STRUCTURE OF AN Fe4S4, CUBANE-LIKE CLUSTER CONTAINING R2dtc LIGANDS Fe4S4(C5H10dtc)4·1/2 CH2Cl2

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作者
刘秋田
黄梁仁
杨瑜
卢嘉锡
机构
[1] Fujian Institute of Research on the Structure of Matter
[2] Academia Sinica
[3] Fuzhou
关键词
Fe; dtc; C5H; CH2Cl2; CUBANE-LIKE CLUSTER CONTAINING R2dtc LIGANDS Fe4S4; Cl;
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摘要
A cubane-like cluster compound FeS(CHdtc)4·1/2CHCl(1) having the highest core oxidation state [FeS]was obtained by combination reaction of dinuclear fragment compound Mg(DMF)[FeSCl] in the presence of CHdtcNa. Compound 1 crystallizes in orthorhombic, space group Pbcn with a=13.917(2), b=18.551
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页码:348 / 348
页数:1
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