Synthesis and Effect of Cation Binding on Photophysical Properties of 1,8-Anthraceno-18-Crown-5

被引：0
|
作者：
Hua JIANG
Hui Jun XU
Pei Jie XIA
Qing Fu ZHOU(Laboratory of Photochemistry
机构：
来源：
ChineseChemicalLetters | 1999年 / 12期
关键词：
Crown ether; photophysical property; canon-binding;
D O I：
暂无
中图分类号：
TQ423 [表面活性剂];
学科分类号：
0817 ;
摘要：
A new type of anthracene crown ether 1, 8-anthraceno-18-crown-5 has been synthesizedand the photophysical properties upon complexation with alkali and alkaline-earth metal canonswere investigated. The fiuorescence quantum yield and lifetime are appreciably enhanced, and thestability constant Ks were determined by fluorometric titration. It was found that the magnitude ofKs is controlled by the size and charge density of the complexed canons.
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页数：4
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