Removal of Trace Olefins from Aromatics Catalyzed by[bmim]Br-AlCl3 Ionic Liquid

被引：0
|
作者：
Jiang Zhenghong
Hou Minghui
Weng Huixin
Shi Li (State Key Lab of Chemical Engineering
机构：
来源：
China Petroleum Processing & Petrochemical Technology | 2010年 / 02期
关键词：
ionic liquid; bromine index; olefins removal; aromatics; catalyst;
D O I：
暂无
中图分类号：
TE624.5 [];
学科分类号：
081702 ;
摘要：
1-Butyl-3-methylimidazolium bromochloroaluminate([bmim]Br-AlCl) ionic liquid was used as an acid catalyst for removal of trace olefins from the aromatic hydrocarbons.The influence of various reaction parameters such as reaction time,temperature,dosage and acid strength of catalyst was investigated.The experimental results demonstrated that the ionic liquid exhibited excellent activity under mild reaction conditions,with the conversion of olefins reaching 98.84%and the bromine index of the aromatics varying from 1129 to 13.On the basis of the results obtained,thereof,a possible reaction mechanism was proposed.
引用
收藏
页码：41 / 44
页数：4
相关论文
共 50 条
  • [21] Synthesis of 5-Benzoylacenaphthene in the Presence of [Bmim]Cl/AlCl3 Ionic Liquid
    Zhu, Shuyun
    Jiang, Deli
    Fang, Yu
    Xie, Jimin
    Chen, Min
    MANUFACTURING SCIENCE AND MATERIALS ENGINEERING, PTS 1 AND 2, 2012, 443-444 : 830 - +
  • [22] CO2-苯-长链烷基苯-[Bmim]Br-AlCl3四元体系相平衡测定
    齐国鹏
    赵锁奇
    孙学文
    精细化工, 2008, (10) : 1037 - 1040
  • [23] Triflic acid-catalyzed adamantylation of aromatics in [BMIM][OTf] ionic liquid; synthetic scope and mechanistic insight
    Laali, KK
    Sarca, VD
    Okazaki, T
    Brock, A
    Der, P
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (06) : 1034 - 1042
  • [24] [Bmim]Br-AlCl3离子液体催化合成二-（3,4-二甲氧基苯基）乙二酮
    张文秀
    陈永杰
    李行
    王思林
    耿秀娟
    精细石油化工, 2012, (03) : 10 - 13
  • [25] Research and application of a non-noble metal catalyst in the removal of trace olefins from aromatics
    Wang, Le
    Meng, Xuan
    Wang, Sitan
    Shi, Li
    Hu, Xiude
    Liu, Naiwang
    NEW JOURNAL OF CHEMISTRY, 2021, 45 (08) : 3901 - 3908
  • [26] Experimental and theoretical study on ionic liquid [Bmim]Br-catalyzed decomposition of cumene hydroperoxide into dimethylbenzyl alcohol
    Zhou, Jinwen
    Sun, Xiuliang
    Huang, Chongpin
    Li, Jianwei
    Chen, Biaohua
    APPLIED CATALYSIS A-GENERAL, 2023, 656
  • [27] Removal of Trace Olefins from Aromatics by Catalytic Alkylation Using 1-Alkyl-3-methylimidazolium Bromochloroaluminate Catalyst
    Sun Yu
    Shi Li(State Key Laboratory of Chemical Engineering
    China Petroleum Processing & Petrochemical Technology, 2011, 13 (02) : 14 - 18
  • [28] Removal of Trace Olefins from Aromatics by Catalytic Alkylation Using 1-Alkyl-3-methylimidazolium Bromochloroaluminate Catalyst
    Sun Yu
    Shi Li
    CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY, 2011, 13 (02) : 14 - 18
  • [29] Electrodeposition of aluminum from [BMIM]Cl/AlCl3 ionic liquids at low temperature
    Kang, Yanhong
    Chen, Shimou
    Zhang, Junling
    Lang, Haiyan
    Zhang, Suojiang
    Huagong Xuebao/CIESC Journal, 2013, 64 (SUPPL.1): : 147 - 154
  • [30] The State of Water in "Ionic Liquid [bmim]Cl/AlCl3/H2O" Systems
    Ubovich, Milosh
    Matveev, Vladimir V.
    Vovk, Mikhail A.
    Chizhik, Vladimir I.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2023, 14 (41): : 9324 - 9328
12345