Solvent-dependent selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under neat conditions

被引：10

作者：

Kai-Jian Liu ^{[1
]}

Tang-Yu Zeng ^{[1
]}

Jia-Le Zeng ^{[1
]}

Shao-Feng Gong ^{[1
]}

Jun-Yi He ^{[2
]}

Ying-Wu Lin ^{[3
]}

Jia-Xi Tan ^{[4
]}

Zhong Cao ^{[2
]}

Wei-Min He ^{[1
,2
]}

机构：

[1] Department of Chemistry, Hunan University of Science and Engineering

[2] Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology

[3] School of Chemistry and Chemical Engineering, University of South China

[4] School of Chemistry and Chemical Engineering, Hunan University of Science and Technology

来源：

Chinese Chemical Letters | 2019年 / 30卷 / 12期

关键词：

5-Hydroxymethylfurfural; 2,5-Furandicarboxylic acid; Base-free; External initiator-free; Dioxygen;

D O I：

暂无

中图分类号：

TQ251.1 [氧杂茂（呋喃）族];

学科分类号：

0817 ;

摘要：

An eco-friendly and economical route for the oxidation of 5-hydroxymethylfurfural(HMF) to 2,5-furandicarboxylic acid(FDCA) with atmospheric dioxygen as the sole oxidant under acid-,base-,metal-,and external initiator-free conditions in minimal solvent was reported.In the present reaction,the 1,2-diethoxyethylane has a dual role:reaction medium and free-radical initiato r.The FDCA easily crystallizes during the reaction and was simple purified via recrystallization to provide the pure FDCA.

引用

页码：2304 / 2308

页数：5

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