CRYSTAL STRUCTURE OF [Ni(（C）6H11O)2PS2)·（C4H9NH2）4]-(C6H11O)2PS2

被引：0
|
作者：
Lin Jian-Hua Xu Zheng You Xiao-ZengCoordination Chemistry Institute
机构：
来源：
Chinese Journal of Structural Chemistry | 1990年 / 03期
关键词：
NH; Ni; CRYSTAL STRUCTURE OF; C4H9NH2; C6H; PS;
D O I：
10.14102/j.cnki.0254-5861.1990.03.011
中图分类号：
学科分类号：
摘要：
[Ni((C6H11O)2PS2)·(C4H9NH2)4](C6H11O)2PS2,Mr-=938. 05, triclinic,P1,a=13. 513(6),b=16. 040 (7), c= 12. 891(6) A , α= 95. 66 (4),β= 90. 23(4),γ= 75. 46(3)°,V = 2691 A3,Z=2,Dc= 1. 16 g·cm3.μ=6. 07cm-1,MoKa radiation, λ=0. 71069 A ,F(000) = 1020,R=0. 100 for 4595 reflections with I≥3σ(I). The title compound molecule consists of a complex cation [Ni((C6H11O)2PS2)(C4H9-NH2)4]+ and a complex anion (C6H11O)2PS2- . The Ni (Ⅱ) atom in the cation is octahedrally coordinated by four nitrogen atoms from four w-butylamine ligands and two sulfur atoms from one (C6H11O)2PS2 group.
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页码：207 / 210
页数：4
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