Solvothermal Synthesis and Crystal Structure of a Zn(Ⅱ) Microporous Metal-organic Framework

被引：0
|
作者：
李东平 [1 ]
李静 [1 ]
李旭 [2 ]
陈萍华 [1 ]
焦晓燕 [1 ]
李永绣 [1 ]
机构：
[1] Department of Chemistry, Nanchang University
[2] Department of Biology and Chemistry, College of Science and Technology, Nanchang University
来源：
Chinese Journal of Structural Chemistry | 2012年 / 31卷 / 11期
关键词：
solvothermal synthesis; Zn(Ⅱ); microporous; metal-organic framework;
D O I：
10.14102/j.cnki.0254-5861.2012.11.021
中图分类号：
O634 [元素有机聚合物];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel three-dimensional Zn(Ⅱ) coordination polymer, Zn3(C2H2N3)4(SiF6), has been synthesized under solvothermal conditions using 1H-1,2,4-triazole-3-carboxylic acid and zinc fluoride as the starting materials. The complex has been characterized by elemental analysis, IR, TG analysis and single-crystal X-ray diffraction analysis. The complex crystallizes in the tetragonal I4/mmm space group with a=11.592(0), c=7.526(1), V=1011.3(2)3 , Z=2, Mr=610.46, Dc=2.005 g/cm3 and F(000)=596. The final R=0.0312 and wR=0.067 for 319 observed reflections with I>2σ(I). In the title complex, the Zn centers are interconnected by μ 3 -bridging triazole ligands to form a microporous three-dimensional metal-organic framework.
引用
收藏
页码：1676 / 1680
页数：5
相关论文
共 50 条
  • [41] SELECTIVE BINDING AND REMOVAL OF GUESTS IN A MICROPOROUS METAL-ORGANIC FRAMEWORK
    YAGHI, OM
    LI, GM
    LI, HL
    NATURE, 1995, 378 (6558) : 703 - 706
  • [42] Flexible sorption and transformation behavior in a microporous metal-organic framework
    Cussen, EJ
    Claridge, JB
    Rosseinsky, MJ
    Kepert, CJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (32) : 9574 - 9581
  • [43] A microporous metal-organic framework for gas chromatographic separation of alkanes
    Chen, Banglin
    Liang, Chengdu, Sr.
    Yang, Jun
    Contreras, Damacio Steven
    Dai, Sheng
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [44] A luminescent microporous metal-organic framework for the recognition and sensing of anions
    Chen, Banglin
    Wang, Liangbo
    Zapata, Fatima
    Qian, Guodong
    Lobkovsky, Emil B.
    Journal of the American Chemical Society, 2008, 130 (21): : 6718 - 6719
  • [45] A luminescent microporous metal-organic framework for the recognition and sensing of anions
    Chen, Banglin
    Wang, Liangbo
    Zapata, Fatima
    Qian, Guodong
    Lobkovsky, Emil B.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (21) : 6718 - +
  • [46] Rational synthesis of microporous metal-organic solids.
    Yaghi, OM
    Li, HL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 552 - INOR
  • [47] A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves
    Denisov, G. L.
    Primakov, P. V.
    Nelyubina, Yu. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2021, 47 (04) : 253 - 260
  • [48] Solvothermal synthesis and photocatalytic activity of metal-organic framework materials based on bismuth and trimesic acid
    Vinh Huu Nguyen
    Lam Van Tan
    Lee, Taeyoon
    Trinh Duy Nguyen
    SUSTAINABLE CHEMISTRY AND PHARMACY, 2021, 20
  • [49] Facile and template-free solvothermal synthesis of mesoporous/macroporous metal-organic framework nanosheets
    Zhang, Boce
    Luo, Yaguang
    Kanyuck, Kelsey
    Saenz, Natalie
    Reed, Kevin
    Zavalij, Peter
    Mowery, Joseph
    Bauchan, Gary
    RSC ADVANCES, 2018, 8 (58): : 33059 - 33064
  • [50] A New Metal-Organic Framework: Product of Solvothermal Synthesis in 3D-Printed Autoclaves
    G. L. Denisov
    P. V. Primakov
    Yu. V. Nelyubina
    Russian Journal of Coordination Chemistry, 2021, 47 : 253 - 260
12345