Two Bisligand-Coordinated Luminescent Zn(Ⅱ)-Coordination Polymers for Sensing of Ions and Pesticides in Aqueous Solutions

被引：0
|
作者：
Zhao-Di Zhou [1 ]
Zi-Long Xu [1 ]
Dan Wang [1 ]
Lin-Fang Jia [1 ]
Han-Qing Zhao [1 ]
Bao-Yi Yu [1 ]
Chong-Chen Wang [2 ]
机构：
[1] Key Laboratory of Urban Agriculture (North China), Ministry of Agriculture, College of Bioscience and Resources Environment, Beijing University of Agriculture
[2] Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation, Beijing University of Civil Engineering and Architecture
来源：
Chinese Journal of Structural Chemistry | 2022年 / 41卷 / 09期
关键词：
D O I：
10.14102/j.cnki.0254-5861.2022-0077
中图分类号：
X832 [水质监测]; O641.4 [络合物化学（配位化学）]; O657.3 [光化学分析法（光谱分析法）];
学科分类号：
摘要：
Two coordination polymers(CPs) [Zn(PTA)(DTP)(H2O)2]·(DMF)(CP-1) and [Zn(BTC)(DTP)]·(CH3CN)1.5·(H2O)4(CP-2) with one-and two-dimensional architectures were synthesized from Zn(Ⅱ) ion and different organic linkers like terephthalic acid(H2PTA), benzene-1,3,5-tricarboxylic acid(H3BTC), and 3,5-di(1,2,4-triazol-1-yl) pyridine(DTP). The fluorescent sensing experiments showed that the two CPs displayed effective, sensitive, and selective abilities towards Fe3+and Cr2O72-. For sensing the pesticides, CP-1 outperforms in sensing of metamitron(MMT) and CP-2 is ultrasensitive towards imidacloprid(IMI). The possible mechanisms involved in the quenching of the fluorescence intensity include the inner filter effect(IFE) and the fluorescence resonance energy transfer(FRET) effect.
引用
收藏
页码：123 / 151
页数：29
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