Synthesis and Crystal Structure of 4-Salicylimine-3,5-bis(2-hydroxyphenyl)-1,2,4-triazole

被引：0

作者：

DU Chen-Xiab ZHU Yub WANG Yangc a(Department of Chemistry

机构：

来源：

Chinese Journal of Structural Chemistry | 2002年 / 03期

关键词：

triazole; hydrogen bond; crystal structure; stacking interaction;

D O I：

10.14102/j.cnki.0254-5861.2002.03.005

中图分类号：

O626 [杂环化合物];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound, 4-salicylimine-3, 5-bis(2-hydroxyphenyl)-1, 2, 4-triazole, was obtained by the condensation reaction of 4-amino-3, 5-bis(2-hydroxyphenyl)-1, 2, 4-triazole with salicylaldehyde in methanol. The crystal structure (C21H16N4O3, Mr = 372.38) belongs to monoclinic system, space group P21/n with a = 10.507(2), b = 16.878(3), c = 11.199(2) ? = 110.86(3), V = 1855.9(6) ?, Z = 4, Dc = 1.333 g/cm3, F(000) = 776, (MoK? = 0.092 mm-1, R = 0.0552 and wR = 0.1095 for 1920 reflections ( I > 2.0(I) ). The analytical results of crystal structure show that there are two different non-covalent interactions in the compound. One is hydrogen bond, and the other p-p stacking interaction. These two types of non-covalent interactions play an important role in the packing of crystal.

引用

页码：252 / 255

页数：4

共 50 条

[41] 4-[4-(dimethylamino)benzylideneamino]-3,5-bis(2-pyridyl)-4H-1,2,4-triazole
Bruno, G
Nicoló, F
Puntoriero, F
Giuffrida, G
Ricevuto, V
Rosace, G
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 : O390 - O391
[42] [Hydrogen bis(1,2,4-triazole)] 1,2,4-triazolium bis(3-carboxy-4-hydroxybenzenesulfonate) 1,2,4-triazole disolvate
Qiu, Ming-qiang
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2029 - U1298
[43] Synthesis, crystal structure and magnetic property of the novel dinuclear nickel(II) complex with 4-(p-methoxyphenyl)-3,5-bis(pyridine-2-yl)-1,2,4-triazole
Zhou, Jun
Yang, Jie
Qi, Li
Shen, Xuan
Zhu, Dunru
Xu, Yan
Song, You
TRANSITION METAL CHEMISTRY, 2007, 32 (06) : 711 - 715
[44] Synthesis, crystal structure and magnetic property of the novel dinuclear nickel(II) complex with 4-(p-methoxyphenyl)-3,5-bis(pyridine-2-yl)-1,2,4-triazole
Jun Zhou
Jie Yang
Li Qi
Xuan Shen
Dunru Zhu
Yan Xu
You Song
Transition Metal Chemistry, 2007, 32 : 711 - 715
[45] Crystal structure of 4-(4-tert-butylphenyl)-3,5-bis(2-pyridyl)-1,2,4-triazole, C22H21N5
Shao, SC
Yang, S
Zhang, SP
Wang, DQ
Zhu, HL
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2004, 219 (03): : 259 - 260
[46] Synthesis, characterisation and DFT studies of [3,5-bis (2-hydroxyphenyl)-1H-1,2,4-triazol-1-yl](phenyl)methanone derivatives
Coetzee, Louis-Charl C.
Muller, Alfred J.
Adeyinka, Adedapo S.
Sonopo, Molahlehi S.
Williams, D. Bradley G.
RESULTS IN CHEMISTRY, 2021, 3
[47] Synthesis, crystal structures, and magnetic properties of three new iron complexes derived from 3,5-bis(pyridin-2-yl)-1,2,4-triazole
Chen, JC
Hu, S
Zhou, AJ
Tong, ML
Tong, YX
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (03): : 475 - 481
[48] A Novel 3D Na(I) Coordination Polymer Constructed by 3,5-Bis(4'-Carboxy-Phenyl)-1,2,4-Triazole: Synthesis, Crystal Structure, and Photocatalytic Property
Lu, J. F.
Gao, J. H.
Tang, B.
Sun, M.
Ge, H. G.
CRYSTALLOGRAPHY REPORTS, 2021, 66 (07) : 1295 - 1299
[49] 3,5-Bis(2-thienyl)-4-amino-1,2,4-triazole as a corrosion inhibitor for copper in acidic media
Tang, Yong-Ming
Chen, Yun
Yang, Wen-Zhong
Yin, Xiao-Shuang
Liu, Ying
Wang, Jin-Tang
ANTI-CORROSION METHODS AND MATERIALS, 2010, 57 (05) : 227 - 233
[50] SYNTHESIS, CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF A LINEAR TRINUCLEAR COPPER(II) COMPOUND WITH CHLORIDE AND 4-AMINO-3,5-BIS(HYDROXYMETHYL)-1,2,4-TRIAZOLE AS BRIDGING LIGANDS
VANKONINGSBRUGGEN, PJ
VANHAL, JW
DEGRAAFF, RAG
HAASNOOT, JG
REEDIJK, J
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (14): : 2163 - 2167

← 1 2 3 4 5 →