Molecularly Imprinted Polymer with Calix[4]arene Derivative for the Recognition of Acetanilide

被引：0

作者：

卢春阳

何海成

何锡文

机构：

[1] State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Department of Chemistry, Nankai University, Tianjin 300071, China ,State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Department of Chemist

[2] Department of Chemistry, Langfang Normal College, Langfang, Hebei 065000, China,State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Department of Chemistry, Nankai University, Tianjin 300071, China

[3] State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China,State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China

来源：

Chinese Journal of Chemistry | 2004年 / 03期

基金：

中国国家自然科学基金;

关键词：

molecularly imprinted polymer (MIP); functional monomer; calixarene; acetanilide;

D O I：

暂无

中图分类号：

O631 [高分子物理和高分子物理化学];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two molecularly imprinted polymers binding to analgesic acetanilide were prepared using either dual functional monomers of calix[4]arene derivative and acrylamide or single monomer acrylamide, respectively. The polymers were ground, sieved and investigated by equilibrium binding experiment to evaluate their recognition properties for the template and other substrates. Scatchard analysis showed that homogeneous recognition sites were formed in the imprinted polymer matrix. Our results demonstrated that the polymer using two functional monomers exhibited better selectivity for the template. This study may open new frontiers for the development and application of imprinted polymers, such as drug separation and purification.

引用

页码：275 / 278 +222

页数：5

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