A Novel Two-dimensional Layer Compound Built up by Hexapolyoxotungstates and Coordinated Sodium Chains

被引：0
|
作者：
蒋晓瑜
肖荔人
张全争
杨文斌
卢灿忠
机构：
[1] Fujian Normal University, Fuzhou, Fujian 350007, China ,State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China ,State Key Laboratory of Structur
[2] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[3] Fujian University of Technology, Fuzhou, Fujian 350007, China ,State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
来源：
Chinese Journal of Structural Chemistry | 2005年 / 05期
基金：
中国国家自然科学基金;
关键词：
crystal structure; hexapolyoxotungstate; building blocks; 2D-layer; coordinated Na;
D O I：
10.14102/j.cnki.0254-5861.2005.05.016
中图分类号：
O627 [元素有机化合物];
学科分类号：
070303 ; 081704 ;
摘要：
The 2D-layer compound ([Na2(C8H12N2O3)4(C2H6SO)4(W6O19)]n 1, Mr = 2133.98) synthesized by the reaction of sodium tungstate and barbitone sodium in the solution of DMSO and water has been characterized by IR and Raman spectra, elemental analysis and TGA. X-ray diffrac- tion analysis indicates that Compound 1 crystallizes in the monoclinic system, space group C2/c with a = 14.8026(4), b = 17.3012(3), c = 19.6379(5) ?, β = 98.6300o, V = 4972.4(2) ?3, Z = 4, F(000) = 3928, Dc = 2.851 and μ = 14.101 mm-1. 1 has a two-dimensional layer structure with hexapolyoxotungstate building blocks and coordinated sodium chains.
引用
收藏
页码：581 / 585 +492
页数：6
相关论文
共 50 条
  • [41] A novel two-dimensional layer network composed of cadmium and bridging isophthalate ligand
    Zheng, CG
    Chen, ZF
    Zhang, J
    Xiong, RG
    You, XZ
    INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (04) : 165 - 167
  • [42] Growth and separation of a start-up vortex from a two-dimensional shear layer
    Sattari, Pooria
    Rival, David E.
    Martinuzzi, Robert J.
    Tropea, Cameron
    PHYSICS OF FLUIDS, 2012, 24 (10)
  • [43] Polymerlike statistical characterization of two-dimensional granular chains
    Wen, Ping-Ping
    Zheng, Ning
    Li, Liang-Sheng
    Li, Heng
    Sun, Gang
    Shi, Qing-Fan
    PHYSICAL REVIEW E, 2012, 85 (03):
  • [44] Markov chains for linear extensions, the two-dimensional case
    Felsner, S
    Wernisch, L
    PROCEEDINGS OF THE EIGHTH ANNUAL ACM-SIAM SYMPOSIUM ON DISCRETE ALGORITHMS, 1997, : 239 - 247
  • [45] Two-dimensional chains and the associated collineations in a complex plane
    Young, JW
    TRANSACTIONS OF THE AMERICAN MATHEMATICAL SOCIETY, 1910, 11 : 280 - 293
  • [46] On Dirichlet eigenvectors for neutral two-dimensional Markov chains
    Champagnat, Nicolas
    Diaconis, Persi
    Miclo, Laurent
    ELECTRONIC JOURNAL OF PROBABILITY, 2012, 17 : 1 - 41
  • [47] Note: Percolation in two-dimensional flexible chains systems
    Pawlowska, Monika
    Zerko, Szymon
    Sikorski, Andrzej
    JOURNAL OF CHEMICAL PHYSICS, 2012, 136 (04):
  • [48] CLASSIFICATION DYNAMICS OF TWO-DIMENSIONAL CHAINS OF EVOLUTION ALGEBRAS
    Murodov, Sh N.
    INTERNATIONAL JOURNAL OF MATHEMATICS, 2014, 25 (02)
  • [49] Sodium pentafluorobenzoate monohydrate: A novel two-dimensional carboxylate polymer with strong sodium-fluorine interactions
    Bruce, Michael I.
    Hall, Benjamin C.
    Skelton, Brian W.
    White, Allan H.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (6-7): : 1111 - 1114
  • [50] TWO-DIMENSIONAL RANDOM COIL CHAINS ON HEXAGONAL LATTICES
    MOM, V
    POLYMER, 1983, 24 (04) : 409 - 416
12345