Application of Substitutional Model in Oxide Systems

被引:0
|
作者
Lin LIDept. Mater. Sci. & Eng.
机构
关键词
Oxide systems; Gibbs free energy; Thermodynamics;
D O I
暂无
中图分类号
O642 [化学热力学、热化学、热力学平衡];
学科分类号
070304 ; 081704 ;
摘要
The application of substitutional model in oxide systems, in comparison with that of sublattice model, is discussed.The results show that in the case of crystalline phases and liquid phases without molecular-like associates or theshortage of element in sublattice, these two models get consistent in the description of the formalism of Gibbs freeenergies of phases and obtain the same result of phase diagram calculation when the valence of the cations keep thesame.
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页码:66 / 68
页数:3
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