Luminescent properties of red phosphors K2Ba(MoO4)2:Eu3+ for white light emitting diodes

被引:8
|
作者
李兆梅 [1 ]
钟迎娟 [1 ]
高绍康 [1 ]
机构
[1] College of Chemistry and Chemical Engineering, Fuzhou University
关键词
K2Ba(MoO4)2:Eu3+; red phosphor; luminescence; charge compensations; rare earths;
D O I
暂无
中图分类号
TN312.8 [];
学科分类号
0803 ;
摘要
K2Ba(MoO4)2:Eu3+ phosphors were synthesized by solid-state reaction. The emission and excitation spectra of K2 Ba(MoO4)2:Eu3+ phosphors exhibited that the phosphors could be effectively excited by near ultraviolet (394 nm) and blue (465 nm) light, and emitted red light at 616 nm. The influence of Eu3+concentration, sintering temperature and charge compensators (K+, Na+ or Li+ ) on the emission intensity were investigated. The results indicated that concentration quenching of Eu3+ was not observed within 30mol.% Eu 3+, 600 oC was a suitable sintering temperature for preparation of K2 Ba(MoO4)2:Eu3+phosphors, and K+ ions gave the best improvement to enhance the emission intensity. The CIE chromaticity coordinates of K2 Ba(MoO4)2:0.05Eu3+phosphor were calculated to be (0.68, 0.32), and color purity was 97.4%.
引用
收藏
页码:990 / 994
页数:5
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