Controlling the Pore Structure and Photocatalytic Performance of the Flexible Fe~Ⅲ Metal-Organic Framework MIL-53(Fe) by Using Surfactants

被引：0
|
作者：
Zhang Dan [1 ]
Yang Ping [1 ]
Zhang Youhua [1 ]
Duan Linhai [1 ]
Meng Xiuhong [1 ]
机构：
[1] School of Chemical Engineering, Guangdong University of Petrochemical Technology
来源：
China Petroleum Processing & Petrochemical Technology | 2021年 / 23卷 / 03期
关键词：
D O I：
暂无
中图分类号：
O643.36 [催化剂]; O644.1 [光化学];
学科分类号：
070304 ; 081704 ; 081705 ;
摘要：
An approach for dominating the channel form of the flexible MIL-53(Fe) was developed by using a surfactantassisted modified method. The surfactant tetraethylammonium hydroxide(TEAOH) can control the channel form of MIL-53(Fe) to be a "closed-pore" form, whereas the surfactant polyoxyethylene polyoxypropylene polyoxyethylene(P123) or polyvinyl alcohol(PVA) can dominate the channel form of MIL-53(Fe) for a "large-pore" form. The photocatalytic performance of MIL-53(Fe) with different channel forms was investigated through the degradation of rhodamine B(Rh B) in water under violet light irradiation. The results showed that MIL-53(Fe) with a "large-pore" form exhibited higher photocatalytic activity than that of MIL-53(Fe) with a "closed-pore" form. MIL-53(Fe) modified with PVA exhibit the best photocatalytic activity for degrading almost 100% Rh B in 90 minutes.
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页码：23 / 29
页数：7
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