Decatungstate as a direct hydrogen atom transfer photocatalyst for synthesis of trifluromethylthioesters from aldehydes

被引：0
|
作者：
Xiaochen Wang [1 ]
Jianyang Dong [1 ]
Yuxiu Liu [1 ]
Hongjian Song [1 ]
Qingmin Wang [1 ,2 ]
机构：
[1] State Key Laboratory of Elemento-Organic Chemistry, Research Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University
[2] Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
来源：
ChineseChemicalLetters | 2021年 / 32卷 / 10期
基金：
中国国家自然科学基金;
关键词：
D O I：
暂无
中图分类号：
TQ225.27 []; O643.36 [催化剂]; O644.1 [光化学];
学科分类号：
070304 ; 0817 ; 081704 ; 081705 ;
摘要：
We have developed a versatile, mild protocol for trifluoromethylthiolation reactions of aldehydes with catalysis by a decatungstate hydrogen atom transfer photocatalyst under redox-neutral conditions. The protocol is highly selective, operationally simple, and compatible with a wide array of sensitive functional groups. It can be used for late-stage functionalization of bioactive molecules, which makes it convenient for drug discovery.
引用
收藏
页码：3027 / 3030
页数：4
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