Stable carbon isotope composition of monoterpanes in essential oils and crude oils

被引：0
|
作者：
ZHANG DaJiang1
2 Key Laboratory of Petroleum Geochemistry
3Geochemistry Department
机构：
来源：
Science China Earth Sciences | 2010年 / 53卷 / 04期
基金：
中国国家自然科学基金;
关键词：
monoterpenoids; stable carbon isotope; essential oil; crude oil;
D O I：
暂无
中图分类号：
P618.13 [石油、天然气];
学科分类号：
0709 ; 081803 ;
摘要：
Twenty-five monoterpanes from six types of essential oils and hydrogenated turpentine oil have been identified and their stable carbon isotope composition determined.Monoterpanes in essential oils sourced from terrestrial higher plants display a δ13C value in the range of-34‰-26‰,and mostly between-29‰ and-27‰.The δ13C value of any single monoterpane is very consistent in different essential oils.Acyclic monoterpanes show closer isotope composition between-28.6‰ and-26.2‰,with an average value of-27.7‰.In contrast,the isotope composition of cyclic monoterpanes is more scattered with an average value of-28.6‰.Isotopic fractionation with 13C enrichment has been observed during both artificial and geological hydrogenation of monoterpenoids to monoterpanes,and this is more obvious for the acyclic monoterpenoids.In addition to higher plants,acyclic monoterpane 2,6-dimethylheptane in crude oil can also be originated from other organic inputs.
引用
收藏
页码：522 / 528
页数：7
相关论文
共 50 条
  • [31] CARBON ISOTOPE COMPOSITION OF KOLPAKOVSKY TROUGH OILS AND GASES (WEST KAMCHATKA)
    KUDRYAVTSEVA, YI
    KRYLOVA, TA
    AVDEYEV, AS
    MAKHOV, SF
    BLOKHINA, GG
    [J]. DOKLADY AKADEMII NAUK SSSR, 1991, 316 (05): : 1212 - 1215
  • [32] FRACTIONATION OF STABLE CARBON ISOTOPES AND THE GENESIS OF SOME CRUDE OILS FROM EGYPT
    ALY, AIM
    HAMZA, MS
    HASHAD, AH
    SWAILEM, FM
    ELSAMIE, SA
    [J]. ISOTOPENPRAXIS, 1984, 20 (05): : 180 - 183
  • [33] BIOGENESIS OF ESSENTIAL OILS - COMPOSITION OF 2 ESSENTIAL OILS OF MENTHA-PULEGIUM L
    HEFENDEHL, FW
    [J]. PHYTOCHEMISTRY, 1970, 9 (09) : 1985 - +
  • [34] METHODS OF DETERMINATION OF NITROGEN ISOTOPE RATIO OF CRUDE OILS
    PLATE, A
    EICHMANN, R
    BEHRENS, W
    KROEPELI.H
    [J]. ERDOL UND KOHLE ERDGAS PETROCHEMIE VEREINIGT MIT BRENNSTOFF-CHEMIE, 1971, 24 (03): : 141 - &
  • [35] COMPOSITION OF UNITED-STATES CRUDE OILS
    SMITH, HM
    [J]. INDUSTRIAL AND ENGINEERING CHEMISTRY, 1952, 44 (11): : 2577 - 2585
  • [36] The Essential Oils Composition of Salvia mirzayanii
    Khajeh, Mostafa
    Ghanbari, Ahmad
    Panjehkeh, Naser
    Kaykhaii, Massoud
    Mirmoghaddam, Majid
    Hashemi, Hossein
    [J]. JOURNAL OF ESSENTIAL OIL BEARING PLANTS, 2010, 13 (04) : 432 - 439
  • [37] Chemical Composition, Antimicrobial and Antitumor Activities of the Essential Oils and Crude Extracts of Euphorbia macrorrhiza
    Lin, Jianbo
    Dou, Jun
    Xu, Jiangling
    Aisa, Haji Akber
    [J]. MOLECULES, 2012, 17 (05) : 5030 - 5039
  • [38] The Impact of the Composition of the Crude Oils on the Wax Crystallization
    Hosseinipour, Arya
    Sabil, Khalik M.
    Ekaputra, Andhy Arya
    Japper, Azuraien B.
    Ismail, Lukman
    [J]. PROCESS AND ADVANCED MATERIALS ENGINEERING, 2014, 625 : 196 - +
  • [39] Ruta Essential Oils: Composition and Bioactivities
    Nahar, Lutfun
    El-Seedi, Hesham R.
    Khalifa, Shaden A. M.
    Mohammadhosseini, Majid
    Sarker, Satyajit D.
    [J]. MOLECULES, 2021, 26 (16):
  • [40] Characterisation of crude oils by carbon and sulphur isotope ratio measurements as a tool for pollution control
    Becker, S
    Hirner, AV
    [J]. ISOTOPES IN ENVIRONMENTAL AND HEALTH STUDIES, 1998, 34 (03) : 255 - 264
12345