Allyltin tribromide: A versatile reagent involved in the ring-opening of epoxides

被引：0
|
作者：
CHEN GuoHong
机构：
来源：
Science China(Chemistry) | 2010年 / 06期
关键词：
versatile reagent; allyltin tribromide; ring opening of epoxides; room temperature;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
070303 ; 081704 ;
摘要：
This paper presents a versatile reagent for epoxide cleavage.The allyltin tribromide could act as a novel and easily prepared allylation reagent and halide atom donor to convert epoxides to the corresponding homoallyl alcohols and halohydrins in high yields with excellent regioselectivities under mild reaction conditions,respectively.It could also act as a Lewis acid to catalyze the ring opening reactions of epoxides with alcohols.
引用
收藏
页码：1294 / 1301
页数：8
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