Allyltin tribromide: A versatile reagent involved in the ring-opening of epoxides

被引：0
|
作者：
CHEN GuoHong
机构：
来源：
Science China(Chemistry) | 2010年 / 06期
关键词：
versatile reagent; allyltin tribromide; ring opening of epoxides; room temperature;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
070303 ; 081704 ;
摘要：
This paper presents a versatile reagent for epoxide cleavage.The allyltin tribromide could act as a novel and easily prepared allylation reagent and halide atom donor to convert epoxides to the corresponding homoallyl alcohols and halohydrins in high yields with excellent regioselectivities under mild reaction conditions,respectively.It could also act as a Lewis acid to catalyze the ring opening reactions of epoxides with alcohols.
引用
收藏
页码：1294 / 1301
页数：8
相关论文
共 50 条
  • [1] Allyltin tribromide: A versatile reagent involved in the ring-opening of epoxides
    GuoHong Chen
    Xin Wang
    XiaoQian Jin
    LingYan Liu
    WeiXing Chang
    Jing Li
    Science China Chemistry, 2010, 53 : 1294 - 1301
  • [2] Allyltin tribromide: A versatile reagent involved in the ring-opening of epoxides
    CHEN GuoHongWANG XinJIN XiaoQianLIU LingYanCHANG WeiXing LI Jing State Key Laboratory and Research Institute of Elementoorganic ChemistryNankai UniversityTianjin China
    Science China(Chemistry), 2010, 53 (06) : 1294 - 1301
  • [3] Allyltin tribromide: A versatile reagent involved in the ring-opening of epoxides
    Chen GuoHong
    Wang Xin
    Jin XiaoQian
    Liu LingYan
    Chang WeiXing
    Li Jing
    SCIENCE CHINA-CHEMISTRY, 2010, 53 (06) : 1294 - 1301
  • [4] RING-OPENING OF CHALCONE EPOXIDES WITH VILSMEIER REAGENT
    AMARESH, RR
    PERUMAL, PT
    TETRAHEDRON LETTERS, 1995, 36 (40) : 7287 - 7288
  • [5] Bis-chlorodibutyltin oxide as a new reagent for a mild, versatile and regioselective ring-opening of epoxides
    Salomon, CJ
    SYNLETT, 2001, (01) : 65 - 68
  • [6] AMINOLEAD COMPOUNDS AS A NEW REAGENT FOR REGIOSELECTIVE RING-OPENING OF EPOXIDES
    YAMADA, J
    YUMOTO, M
    YAMAMOTO, Y
    TETRAHEDRON LETTERS, 1989, 30 (32) : 4255 - 4258
  • [7] POTASSIUM DIHYDROGEN TRIFLUORIDE - A NOVEL FLUORINATING REAGENT FOR RING-OPENING OF EPOXIDES
    TAMURA, M
    SHIBAKAMI, M
    ARIMURA, T
    KUROSAWA, S
    SEKIYA, A
    JOURNAL OF FLUORINE CHEMISTRY, 1995, 70 (01) : 1 - 3
  • [8] Ring-Opening of Epoxides in Water
    Bonollo, Simona
    Lanari, Daniela
    Vaccaro, Luigi
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 2011 (14) : 2587 - 2598
  • [9] Mechanochemical Ring-Opening of Allylic Epoxides
    Barbee, Meredith H.
    Wang, Junpeng
    Kouznetsova, Tatiana
    Lu, Meilin
    Craig, Stephen L.
    MACROMOLECULES, 2019, 52 (16) : 6234 - 6240
  • [10] RING-OPENING REACTIONS OF DELTACYCLENE EPOXIDES
    LAUTENS, M
    CRUDDEN, CM
    TETRAHEDRON LETTERS, 1989, 30 (36) : 4803 - 4806
12345