金属有机框架UiO-66-（COOH）2吸附亚甲基蓝的作用机制

被引：2
|
作者：
王洪婷
罗时万
郭志伟
张蓉
杨犁
覃远航
机构：
[1] 武汉工程大学化工与制药学院,绿色化工过程教育部重点实验室(武汉工程大学),新型反应器与绿色化工技术湖北省重点实验室(武汉工程大学)
来源：
武汉工程大学学报 | 2023年 / 45卷 / 02期
关键词：
UiO-66; 吸附; 亚甲基蓝; 作用机制;
D O I：
10.19843/j.cnki.CN42-1779/TQ.202204028
中图分类号：
X703 [废水的处理与利用]; TQ424 [吸附剂];
学科分类号：
摘要：
为减少染料废水的排放造成的环境污染，分别采用溶剂热法和机械搅拌法制备了金属有机骨架材料UiO-66和羧基改性材料UiO-66-（COOH）2，研究了两种吸附剂对有机染料亚甲基蓝（MB）的吸附性能，并探讨了相应的吸附机理。结果表明：UiO-66和UiO-66-（COOH）2对MB均具有较好的吸附能力，UiO-66-（COOH）2对MB的平衡吸附量达416.95 mg/g，比UiO-66材料提高了38.6%。UiO-66-（COOH）2对MB的高效吸附是静电相互作用、π-π相互作用和氢键作用等多重机制共同作用的结果。吸附过程符合拟二级动力学模型，吸附平衡符合Freundlich吸附模型。
引用
收藏
页码：139 / 147
页数：9
相关论文
共 32 条
  • [11] Efficient removal of acid dyes using permanent magnetic resin and its preliminary investigation for advanced treatment of dyeing effluents[J] . Ji Wu,Qimeng Li,Wentao Li,Yan Li,Guoxiang Wang,Aimin Li,Haibo Li.Journal of Cleaner Production . 2020 (C)
  • [12] Polycarboxyl metal–organic framework UiO-66-（COOH）＜Subscript＞2＜/Subscript＞ as efficient desorption/ionization matrix of laser desorption/ionization mass spectrometry for selective enrichment and detection of phosphopepti[J] . Yingchen Yang,Yan Xia.Journal of Nanoparticle Research . 2019 (11)
  • [13] Removal of Co(II) from aqueous solution with functionalized metal–organic frameworks (MOFs) composite
    Guoyuan Yuan
    Yin Tian
    Min Li
    Yang Zeng
    Hong Tu
    Jiali Liao
    Jijun Yang
    Yuanyou Yang
    Ning Liu
    [J]. Journal of Radioanalytical and Nuclear Chemistry, 2019, 322 : 827 - 838
  • [14] Polyacids as Modulators for the Synthesis of UiO-66
    Bentz, Kyle C.
    Ayala, Sergio, Jr.
    Kalaj, Mark
    Cohen, Seth M.
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 2019, 72 (10) : 848 - 851
  • [15] Hybrid anaerobic-aerobic biological treatment for real textile wastewater[J] . Rabia Shoukat,Sher Jamal Khan,Yousuf Jamal.Journal of Water Process Engineering . 2019
  • [16] Adsorption Equilibrium of Carbon Dioxide, Methane, Nitrogen, Carbon Monoxide, and Hydrogen on UiO-66（Zr）COOH2[J] . M. A. Moreira,R. O. M. Dias,U.-Hwang Lee,Jong-San Chang,A. M. Ribeiro,A. F. P. Ferreira,A. E. Rodrigues.Journal of Chemical ＆ Engineering Data . 2019 (11)
  • [17] An integrated permanganate and ozone process for the treatment of textile dyeing wastewater: Efficiency and mechanism[J] . Jieying Liang,Xun-An Ning,Jian Sun,Jian Song,Yanxiang Hong,Haili Cai.Journal of Cleaner Production . 2018
  • [18] Controlled incorporation homogeneous Ti-doped SBA-15 for improving methylene blue adsorption capacity[J] . Taotao Qiang,Yunying Song,Jing Zhao,Ji Li.Journal of Alloys and Compounds . 2018
  • [19] Facile synthesis of magnetic hybrid metal–organic frameworks with high adsorption capacity for methylene blue[J] . Rui Wang,Chunhua Ge,Tianzhu Xing,Yuanyuan Zhang,Yundi Zhang,Xiangdong Zhang.Applied Organometallic Chemistry . 2017 (11)
  • [20] Preparation of piperazine-grafted amine-functionalized UiO-66 metal organic framework and its application for CO2 over CH4 separation
    Vahidi, Mehdi
    Rashidi, Ali Morad
    Tavasoli, Ahmad
    [J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2017, 14 (10) : 2247 - 2253
1234