Two highly porous single-crystalline zirconium-based metal-organic frameworks

被引：0
|
作者：
Wen-Yang Gao [1 ]
Timmy Thiounn [1 ]
Lukasz Wojtas [1 ]
Yu-Sheng Chen [2 ]
Shengqian Ma [1 ]
机构：
[1] Department of Chemistry, University of South Florida
[2] ChemMatCARS, Center for Advanced Radiation Sources, University of Chicago
来源：
Science China(Chemistry) | 2016年 / 08期
基金：
美国国家科学基金会;
关键词：
metal-organic frameworks; zirconium cluster; single-crystalline;
D O I：
暂无
中图分类号：
O627 [元素有机化合物];
学科分类号：
070303 ; 081704 ;
摘要：
Herein we report two highly porous Zr-based metal-organic frameworks（MOFs, 1 and 2） constructed by the truncated octahedral secondary building unit（SBU） of Zr;O;（OH）;（CO;）;and the organic linear ligand of 4,4.-stilbenedicarboxylic acid（H;sbdc） or4,4′-azobenezenedicarboxylic acid（H;abdc）. Both Zr-based MOFs are obtained as single crystals of suitable size for single-crystal X-ray diffraction analysis. Furthermore, these two Zr-based MOFs have been fully characterized by powder X-ray diffraction（PXRD） studies, thermogravimetric analysis（TGA）, infrared spectroscopy（IR） and gas adsorption analysis. In particular, their CO;gas adsorption behaviors have been investigated and discussed.
引用
收藏
页码：980 / 983
页数：4
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