Studies on solid state reactions of coordination compounds

被引：0

作者：

LⅩⅢ.Solid state synthesis of a series of tetranuclear Mo(W)-Ag mixed-metal clusters.Crystal structures of ^{[4
]}

机构：

来源：

Chinese Journal of Chemistry | 1993年 / 05期

基金：

中国国家自然科学基金;

关键词：

AgBr;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A series of tetranuclear Mo（W）-Ag mixed-metal clusters have been synthesized by makinguse of the solid state reactions of[NH][MYS]（M=Mo,W;Y=O,S）,AgX（X=Cl,Br,I）and（n-Bu）NX’（X’=Cl,Br）,two of which[（n-Bu）N][MoOSAgBr]（1）and[（n-Bu）N][WSAgCl]（2）have been structurally characterized by X-ray analysis.The crystal data:1,cubic,P 3m,a=12.093（4） ,Z=1,R=0.076;2,cubic,P 3m,a=12.059（2） ,Z=1,R=0.075.The clusteranion core[AgMSX’]of the two compounds can be viewed as a cube in which the four metal atomsand the four non-metal atoms are statistically distributed,respectively.Substitution reaction withPPhligand is also discussed for this type of tetranuclear clusters.

引用

页码：418 / 424

页数：7

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