Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl3·6H2O/BF3·（Et）2O in ethanol

被引：0

作者：

Xiuquan Jia ^{[1
,2
]}

Jiping Ma ^{[1
]}

Penghua Che ^{[1
,2
]}

Fang Lu ^{[1
]}

Hong Miao ^{[1
]}

Jin Gao ^{[1
]}

Jie Xu ^{[1
]}

机构：

[1] Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences

[2] Graduate University of Chinese Academy of Sciences

来源：

Journal of Energy Chemistry | 2013年 / 01期

基金：

中国国家自然科学基金;

关键词：

carbohydrates; 5-ethoxymethylfurfural; catalysis; Lewis acid;

D O I：

暂无

中图分类号：

O643.32 [催化反应];

学科分类号：

081705 ;

摘要：

Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural (EMF) catalyzed by Lewis acid in ethanol was investigated. It was found that BF3(Et)2O was favorable for 5-hydroxymethylfurfural (HMF) etherification to EMF. BF3(Et)2O combination with AlCl3 6H2O with the molar ratio of 1 was an effective catalyst system for synthesis of EMF from fructose-based carbohydrates. 55.0%, 45.4% and 23.9% of EMF yields were obtained from fructose, inulin and sucrose under optimized conditions, respectively.

引用

页码：93 / 97

页数：5

共 50 条

[31] 肟和酰胺在水合介质中用AlCl3·6H2O/KI/H2O/CH3CN体系脱水
沈蓓苓
中国医药工业杂志, 2003, (10) : 32 - 32
[32] Experiment and prediction for the solubility of AlCl3·6H2O in FeCl3, CaCl2, KCl and KCl-FeCl3solutions
Cheng W.
Li J.
Xu L.
Cheng F.
Liu G.
Huagong Xuebao/CIESC Journal, 2023, 74 (02): : 642 - 652
[33] Synthesis of alumina aerogels from AlCl3•6H2O with an aid of acetoacetic-grafted polyvinyl alcohol
Zhang, Xiaokang
Zhang, Rui
Jin, Shuangling
Hu, Zhen
Liu, Yan
Jin, Minglin
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2018, 87 (02) : 486 - 495
[34] Low pressure synthesis of boron nitride with (C2H5)2O• BF3 and Li3N precursor
Wang, SB
Xu, XW
Fan, HL
Li, YP
JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY, 2005, 12 (01): : 60 - 63
[35] Synthesis of alumina aerogels from AlCl3·6H2O with an aid of acetoacetic-grafted polyvinyl alcohol
Xiaokang Zhang
Rui Zhang
Shuangling Jin
Zhen Hu
Yan Liu
Minglin Jin
Journal of Sol-Gel Science and Technology, 2018, 87 : 486 - 495
[36] AlCl3•6H2O as a Catalyst for Simple and Efficient Synthesis of gem-Dihydroperoxides from Ketones and Aldehydes using Aqueous H2O2
Azarifar, D.
Khosravi, K.
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2011, 8 (04) : 1006 - 1013
[37] Low pressure synthesis of boron nitride with (C2H5)2O · BF3 and Li3N precursor
Shao-bo Wang
Xiao-wei Xu
Hui-li Fan
Yu-ping Li
Journal of Central South University of Technology, 2005, 12 : 60 - 63
[38] Low pressure synthesis of boron nitride with (C2H5)2O·BF3 and Li3N precursor
王少波
徐晓伟
范慧丽
李玉萍
Journal of Central South University, 2005, (01) : 60 - 63
[39] AlCl3·6H2O在Fe(Ⅲ)-K-Ca-Cl-H2O体系中溶解度的测定
付梦源
程文婷
程芳琴
中国科技论文, 2015, 10 (24) : 2856 - 2862
[40] NUCLEAR MAGNETIC RESONANCE STUDIES OF BF3 ADDITION COMPOUNDS .1. EXCHANGE OF BF3 BETWEEN (CH3)2O.BF3 AND (C2H5)2O.BF3
RUTENBERG, AC
PALKO, AA
DRURY, JS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (18) : 2702 - &

← 1 2 3 4 5 →