Perovskite type SrCoFeO(SCF) membrane and a novel perovskite-related ZrOdopedSrCoFeO(SCFZ) membrane were successfully prepared by isostatic pressing.The sintered membraneswere characterized by high-temperature X-ray diffeaction (HTXRD) and energy dispersive spectroscopy (EDS).Theoxygen permeabilities of membranes have been measured in the temperature range of 923 K to 1243K.The oxygenpermeation fiux at 1l23K and activaion energy of SCFZ membrane with the thickness of 2mm are respectively2.68×10mol.cm.minand 97.76kJ.mol.The results of HTXRD in argon atmosphere and the oxygen per-meation experiment indicate that the SCFZ membrane is stable at elevated temperature and low oxygen partialpressure.