KINETICS OF METHANE PARTIAL OXIDATION TO FORMALDEHYDE OVER SILICA

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ZHONG Lin QIU Fa-Li ZHAO Ming-Ying Chengdu Institute of Organic Chemistry
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HCHO; KINETICS OF METHANE PARTIAL OXIDATION TO FORMALDEHYDE OVER SILICA;
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Treated silica was found to be active for methane partial oxidationto formaldehyde.The results of kinetic study show that the formation rate ofHCHO was first order with respect to CHand zero order with respect toOand the apparent activation energy of CO had two different values,239.67kJ/mol at lower temperature and 353.17kJ/mol at higher temperature,The formation of HCHO was considered to be related to active oxygen on sil-ica surface.
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页码:363 / 374
页数:12
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