X-ray absorption study of tribofilms from ZDDP and overbased salicylate detergents

被引：0
|
作者：
M.Kasrai [1 ]
G.M.Bancroft [1 ]
机构：
[1] Department of Chemistry,University of Western Ontario,London
来源：
ChineseChemicalLetters | 2009年 / 20卷 / 01期
关键词：
ZDDP; Salicylate detergent; Surface chemistry; XANES analysis;
D O I：
暂无
中图分类号：
TQ649 [合成洗涤剂工业];
学科分类号：
0817 ;
摘要：
The interaction of overbased salicylate detergents with zinc dialkyldithiophosphates（ZDDP）and its effect on the formation of tribofilms under boundary lubrication have been studied by means of X-ray absorption near-edge structure spectroscopy.The results show that addition of metallic detergents to neat ZDDP results in the change of surface chemistry of the tribofilm formed from neat ZDDP.Calcium from detergents is digested in the tribofilm.For the high overbased detergents,the deposit of overbasing agent CaCO;in the tribofilm is also observed along with the formation of calcium phosphate in tdbofilms.
引用
收藏
页码：119 / 122
页数：4
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