Determination of vinyl orientation of mouse neuroglobin by 2D nuclear Overhauser spectroscopy

被引：0
|
作者：
Su Yuan Zhou
机构：
来源：
ChineseChemicalLetters | 2007年 / 03期
关键词：
Heme; Vinyl orientation; Neuroglobin;
D O I：
暂无
中图分类号：
O657.3 [光化学分析法（光谱分析法）];
学科分类号：
摘要：
1H NMR has been used to determine the 2-,4-vinyl orientation of heme active site from oxidized mouse neuroglobin (mNgb).The NOEs between 3-methyl and Hα, Hβ of 2-vinyl, together with the NOEs between 5-methyl and Hα, Hβ of 4-vinyl, allowed the unambiguous determination of trans and cis orientations for the 2- and 4-vinyl groups in the mNgb, respectively.
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页码：319 / 321
页数：3
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