Study on the inclusion compound of β-cyclodextrin with (η5-cyclopentadienyl)tricarbonylmanganese(0)

被引：0
|
作者：
SONG
机构：
来源：
ChineseJournalofChemistry | 1995年 / 04期
基金：
美国国家科学基金会;
关键词：
Inclusion compound; β-cyclodextrin; supermolecule;
D O I：
暂无
中图分类号：
O621 [有机化学一般性问题];
学科分类号：
摘要：
The supramolecular inclusion compound of β-cyclodextrin (β-CD, host) with (η5-cyclopentadienyl)tricarbonylmanganese [MnCp(CO)3, guest] was obtained in a crystalline state. The host-guest compound is thermally stable and do not liberate the guest on heating at 100$ in vacuum. It was characteried by elemental analysis,1H NMR, differential scanning thermal (DSC) analysis and TLC. Continueous variation plot by NMR method shows that β-CD formed 1:1 inclusion compound with MnCp(CO)3. On the basis of 1H NMR spectra and the model building with Corey Pauling Koltum (CPK) models, the most probable inclusion mode is proposed.
引用
收藏
页码：311 / 317
页数：7
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