A New Dinuclear Cu(Ⅱ) Complex of a Ligand with Benzimidazole Group─Synthesis and Crystal Structure

被引：0

作者：

李庆祥 ^{[1
]}

王修峰 ^{[1
]}

杨祥良 ^{[2
]}

徐辉碧 ^{[2
]}

机构：

[1] Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology, Wuhan Institute of Technology

[2] College of Life Science, Huazhong University of Science and Technology

来源：

Chinese Journal of Structural Chemistry | 2007年 / 06期

基金：

中国国家自然科学基金;

关键词：

crystal structure; benzimidazole; dinuclear Cu(Ⅱ) complex;

D O I：

10.14102/j.cnki.0254-5861.2007.06.017

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

A new dinuclear copper complex, [Cu(C9H11N3)Cl2]2 (C18H22Cl4Cu2N6), has been synthe- sized and characterized by X-ray structure determination. It crystallizes in the triclinic P1 space group with a = 7.526(3), b = 9.473(4), c = 9.535(3) , α = 117.214(10), β = 108.251(9), γ = 91.560(6)o, V = 562.3(4) 3, Z = 1, Mr = 591.30, F(000) = 298, Dc = 1.746 g/cm3, μ(MoKα) = 2.385 mm-1, the final R = 0.0577 and wR = 0.1248 for 2188 unique reflections with 1629 observed ones (I > 2σ(I)). In the title complex, each copper(II) atom is located at the center of a distorted trigonal bipyramid of five coordination atoms (two nitrogen and three chlorine atoms). Two copper(II) atoms were bridged by two chlorine anions (Cl(2) and Cl(2a)) to form a Cu(II)-Cu(II) binuclear entity with the distance between two copper(II) atoms of 3.398 .

引用

页码：707 / 710

页数：4

共 50 条

[41] Synthesis and Crystal Structure of a Dinuclear Cu(II) Complex with Tridentate Schiff Base and Azido Bridge
LIN Honga b FENG Yun Longa GAO Shanc aInstitute of Physical Chemistry Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces Zhejiang Normal University Jinhua China b Jinhua Professionaltechnical College Jinhua China c College of Chemistry and Chemical Engineering Heilongjiang University Harbin China
结构化学, 2005, (04) : 375 - 378+365
[42] Synthesis and crystal structure of a dinuclear Cu(II) complex with tridentate Schiff base and azido bridge
Lin, H
Feng, YL
Gao, S
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (04) : 375 - 378
[43] Synthesis and structure of a new dinuclear uranyl complex
Liu, SY
Liu, YS
Zhang, WX
Ma, CQ
Jiang, DH
CHINESE CHEMICAL LETTERS, 2002, 13 (06) : 583 - 586
[44] Study on Synthesis and Crystal Structure of an Unexpected Dialkoxo-Bridged Dinuclear Cu(II) Complex
Dong, Wen-Kui
Zhang, Shou-Ting
Sun, Yin-Xia
Wang, Yuan
Wang, Li
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (04) : 583 - 589
[45] Synthesis and Crystal Structure of a Dinuclear Cu(II) Complex with Tridentate Schiff Base and Azido Bridge
LIN Honga
Chinese Journal of Structural Chemistry, 2005, (04) : 375 - 378
[46] Synthesis and crystal structure of a new dinuclear manganese(II) complex of a macrocyclic ligand with multi-ligating pendant-arms
Luo, YX
Zhang, JR
Lu, LD
Qian, M
Wang, X
Yang, XJ
Jian, FF
TRANSITION METAL CHEMISTRY, 2002, 27 (05) : 469 - 472
[47] Synthesis and crystal structure of a new dinuclear manganese(II) complex of a macrocyclic ligand with multi-ligating pendant-arms
Yuanxiang Luo
Jiangrun Zhang
Lude Lu
Ming Qian
Xin Wang
Xujie Yang
Fangfang Jian
Transition Metal Chemistry, 2002, 27 : 469 - 472
[48] Crystal structure and DNA-binding studies of a new Cu(II) complex involving benzimidazole
Zhou, QH
Yang, P
INORGANICA CHIMICA ACTA, 2006, 359 (04) : 1200 - 1206
[49] Synthesis, Crystal Structure, and Properties of a Dinuclear Cu(I) Cluster
Huo, Lili
Chai, Wenxiang
Song, Li
Zhang, Xiaoli
Tian, Qingxia
Liang, Jiaping
Shi, Hongsheng
Shu, Kangying
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2013, 188 (10) : 1340 - 1350
[50] Synthesis, crystal structure and spectroscopic properties of a dinuclear nickel(II) complex bridged by an alkoxide and a μ-pyrazolate ligand
Kara, H
Elerman, Y
Elmali, A
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2003, 58 (10): : 955 - 958

← 1 2 3 4 5 →