Theoretical Studies on the Third-order Nonlinear Optical Properties and Two-photon Absorption of Stilbene Derivatives

被引：0

作者：

任爱民

封继康

刘孝娟

机构：

[1] State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry , Jilin University, Changchun, Jilin 130023, China,State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry , Jil

[2] College of Chemistry, Jilin University, Changchun, Jilin 130023, China ,State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry , Jilin University, Changchun, Jilin 130023, China

来源：

ChineseJournalofChemistry | 2004年 / 03期

基金：

中国国家自然科学基金;

关键词：

stilbene derivative; electronic spectrum; two-photon absorption cross-section;

D O I：

暂无

中图分类号：

O647.3 [吸附];

学科分类号：

摘要：

Different types of stilbene derivatives (D-p-D, A-p-A, D-p-A) were investigated with AM1, and specially, equilibrium geometries of symmetrical stilbene derivatives (D-p-D) were studied using of PM3. With the same method INDO/CI, the UV-vis spectra were explored and the position and strength of the two-photon absorption were predicated by Sum-Over-States expression. The relationships of the structures, spectra and nonlinear optical properties have been examined. The influence of various substituents on two photon absorption cross-sections was discussed micromechanically.

引用

页码：243 / 251 +220

页数：10

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