Effect of Water on Extractive Desulfurization of Simulated FCC Gasoline Using Ionic Liquid NMP-FeCl3-H2O

被引:0
|
作者
Fang Liuya [1 ]
Shen Zhi [1 ]
Shen Xizhou [1 ]
Kang Shunji [1 ]
Huang Wei [2 ]
Song Hao [3 ]
Liang Tian [1 ]
机构
[1] Key Laboratory for Green Chemical Process, Ministry of Education, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology
[2] The College of Post and Telecommunication, Wuhan Institute of Technology
[3] SINOPEC Research Institute of Petroleum Processing
关键词
ferric chloride; N-methylpyrrolidone; water; activation mechanism;
D O I
暂无
中图分类号
TE624.55 [];
学科分类号
081702 ;
摘要
A series of novel aqueous ionic liquids(NMP-FeCl-nHO) were prepared and the effects of water in the aqueous ionic liquids on desulfurization rate and selectivity of simulated FCC gasoline were investigated. The results showed that adding a small amount of water into the ionic liquid NMP-FeCl3 could effectively improve the desulfurization rate and selectivity, and the optimal amount of water was equal to 5%―10% of NMP. Finally, the possible desulfurization mechanism activated by a small amount of water was proposed.
引用
收藏
页码:121 / 131
页数:11
相关论文
共 50 条
  • [31] COMPLEXATION IN THE LIQUID PHASE OF THE FECL3-HCL-H2O SYSTEM
    DYBINA, PV
    ZHURNAL FIZICHESKOI KHIMII, 1962, 36 (02): : 260 - 265
  • [32] Oxidative desulfurization of diesel fuel using a Bronsted acid room temperature ionic liquid in the presence of H2O2
    Zhao, Dishun
    Wang, Jianlong
    Zhou, Erpeng
    GREEN CHEMISTRY, 2007, 9 (11) : 1219 - 1222
  • [33] Catalytic oxidative desulfurization with a hexatungstate/aqueous H2O2/ionic liquid emulsion system
    Ding, Yuxiao
    Zhu, Wenshuai
    Li, Huaming
    Jiang, Wei
    Zhang, Ming
    Duan, Yuqing
    Chang, Yonghui
    GREEN CHEMISTRY, 2011, 13 (05) : 1210 - 1216
  • [34] Extractive desulfurization of crude petroleum oil and liquid fuels using trihexyl tetradecyl phosphonium bis(2-ethylhexyl) phosphate ionic liquid
    Solouki, Amin
    Chaouki, Jamal
    CHEMICAL PRODUCT AND PROCESS MODELING, 2024, 19 (02): : 263 - 273
  • [35] A Study on the Oxidation-extraction Desulfurization of FCC Gasoline Over Supported Phosphotungstic Acid/H2O2/Dimethyl Sulfoxide (DMSO)
    Cai, T. -F.
    Li, H. -P.
    Zhao, H.
    PETROLEUM SCIENCE AND TECHNOLOGY, 2014, 32 (14) : 1713 - 1719
  • [36] Basic ionic liquid/FeCl3•6H2O as an efficient catalyst for AGET ATRP of methyl methacrylate
    Deng, Zhijun
    Qiu, Lihua
    Bai, Liangjiu
    Zhou, Yinxia
    Lin, Bencai
    Zhao, Jie
    Cheng, Zhenping
    Zhu, Xiulin
    Yan, Feng
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (08) : 1605 - 1610
  • [37] Photooxidative-extractive deep desulfurization of diesel using Cu-Fe/TiO2 and eutectic ionic liquid
    Zaid, Hayyiratul Fatimah Mohd
    Chong, Fai Kait
    Mutalib, Mohamed Ibrahim Abdul
    FUEL, 2015, 156 : 54 - 62
  • [38] The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface
    Kalisz, Justyna
    Nogala, Wojciech
    Adamiak, Wojciech
    Gocyla, Mateusz
    Girault, Hubert H.
    Opallo, Marcin
    CHEMPHYSCHEM, 2021, 22 (13) : 1352 - 1360
  • [39] FeCl3•6H2O catalysed condensation of aldehydes and ketones in ionic liquid:: a novel green synthesis of chalcones
    Zhang, XY
    Niu, HY
    Wang, JJ
    JOURNAL OF CHEMICAL RESEARCH, 2003, (01) : 33 - 35
  • [40] A novel green preparation of α, α′-bis (substituted benzylidene)cycloalkanones promoted by FeCl3•6H2O in ionic liquid
    Zhang, XY
    Fan, XS
    Niu, HY
    Wang, JJ
    CHINESE CHEMICAL LETTERS, 2003, 14 (10) : 1005 - 1007