Visible-light-mediated tungsten-catalyzed C–H amination of unactivated alkanes with nitroarenes

被引：0
|
作者：
Qing Wang [1 ]
Shengyang Ni [1 ]
Xiaochen Wang [1 ]
Yi Wang [1 ]
Yi Pan [1 ]
机构：
[1] State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
来源：
Science China(Chemistry) | 2022年 / 04期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
D O I：
暂无
中图分类号：
O622.6 [含氮化合物];
学科分类号：
摘要：
Alkylamines are important motifs in pharmaceutical and material sciences. The existing reports of C–H amination are limited to ammonia, diazo and azide nitrogen sources. This work describes a rapid construction of C–N bonds from accessible nitroarene and alkane feedstock under decatungstate catalysis. A variety of C–H precursors including gaseous, linear, cyclic and benzylic hydrocarbons could adopt this protocol to afford the corresponding alkylamines in high efficiency.
引用
收藏
页码：678 / 685
页数：8
相关论文
共 50 条
  • [31] Visible-light-mediated eosin Y catalyzed aerobic desulfurization of thioamides into amides
    Yadav, Arvind K.
    Srivastava, Vishnu P.
    Yadav, Lal Dhar S.
    NEW JOURNAL OF CHEMISTRY, 2013, 37 (12) : 4119 - 4124
  • [32] Visible-Light-Mediated β-C(sp3)-H Amination of Glycosylimidates:En Route to Oxazoline-Fused/Spiro Nonclassical Bicyclic Sugars
    Shaw, Mukta
    Kumar, Amit
    ORGANIC LETTERS, 2019, 21 (09) : 3108 - 3113
  • [33] Visible-Light-Mediated Rose Bengal-Catalyzed α-Hydroxymethylation of Ketones with Methanol
    Yang, Jingya
    Xie, Dongtai
    Zhou, Hongyan
    Chen, Shuwen
    Duan, Jiaokui
    Huo, Congde
    Li, Zheng
    ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (18) : 3471 - 3476
  • [34] Visible-Light-Induced Synergistic W/Cr Catalyzed gem-Difluoroallylation of Unactivated Alkanes
    Zhang, Zhijie
    Zhang, Yue
    Xie, Xinyu
    Liu, Hua-Wei
    Zhu, Tianshuai
    Zhang, Jing-Jing
    Hu, Meng-Yang
    Chen, Zhen
    ORGANIC LETTERS, 2025, 27 (08) : 2016 - 2021
  • [35] Organic-Dye-Catalyzed Visible-Light-Mediated Regioselective C-3 Alkoxycarbonylation of Imidazopyridines by Carbazates
    Kshirsagar, Umesh A.
    Sarothiya, Durgesh
    Bhawale, Rajesh T.
    JOURNAL OF ORGANIC CHEMISTRY, 2022, 87 (21): : 14915 - 14922
  • [36] Visible-Light-Mediated C(sp3)-H Thiocarbonylation for Thiolactam Preparation with Potassium Sulfide
    Tan, Wei
    Wang, Cuihong
    Jiang, Xuefeng
    CHINESE JOURNAL OF CHEMISTRY, 2019, 37 (12) : 1234 - 1238
  • [37] Visible-Light-Mediated Carbonyl Alkylative Amination to All-Alkyl α-Tertiary Amino Acid Derivatives
    Blackwell, J. Henry
    Kumar, Roopender
    Gaunt, Matthew J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (03) : 1598 - 1609
  • [38] Visible-Light-Mediated Photoredox-Catalyzed Regio- and Stereoselective Chlorosulfonylation of Alkynes
    Chakrasali, Prashant
    Kim, Kyuneun
    Jung, Young-Sik
    Kim, Hyejin
    Han, Soo Bong
    ORGANIC LETTERS, 2018, 20 (23) : 7509 - 7513
  • [39] Visible-Light-Mediated, Organophotocatalytic C-H Thiocyanation of Pyrazolo[1,5-a]pyrimidines
    Pattanayak, Paramita
    Satyanarayana, Appanapalli N. V.
    Chatterjee, Tanmay
    JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (18): : 13215 - 13223
  • [40] Mechanism of the Visible-Light-Mediated Copper-Catalyzed Coupling Reaction of Phenols and Alkynes
    Xiao, Pin
    Li, Chun-Xiang
    Fang, Wei-Hai
    Cui, Ganglong
    Thiel, Walter
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (44) : 15099 - 15113
12345