Visible-light-mediated tungsten-catalyzed C–H amination of unactivated alkanes with nitroarenes

被引：0
|
作者：
Qing Wang [1 ]
Shengyang Ni [1 ]
Xiaochen Wang [1 ]
Yi Wang [1 ]
Yi Pan [1 ]
机构：
[1] State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
来源：
Science China(Chemistry) | 2022年 / 04期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
D O I：
暂无
中图分类号：
O622.6 [含氮化合物];
学科分类号：
摘要：
Alkylamines are important motifs in pharmaceutical and material sciences. The existing reports of C–H amination are limited to ammonia, diazo and azide nitrogen sources. This work describes a rapid construction of C–N bonds from accessible nitroarene and alkane feedstock under decatungstate catalysis. A variety of C–H precursors including gaseous, linear, cyclic and benzylic hydrocarbons could adopt this protocol to afford the corresponding alkylamines in high efficiency.
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收藏
页码：678 / 685
页数：8
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