Synthesis of a New Ligand Containing 1, 7-Diaza-12-crown-4 and the Application in Asymmetric Cyclopropanation Reaction

被引:0
|
作者
Cheng Yun WANG
机构
关键词
S; S)-1; 7-Bis (4-benzyloxazolin-2-yl-methyl)-1; 7-diaza-12-crown-4; asymmetric cy-clopropanation;
D O I
暂无
中图分类号
O641 [结构化学];
学科分类号
070304 ; 081704 ;
摘要
A new chiral multidenate ligand (S, S)-1,7-bis(4-benzyloxazolin-2-yl-methyl)-1, 7-diaza- 12-crown-4 1 has been synthesized and used as ligand in the copper catalyzed asymmetric cyclopropanation of 1, 1-diphenylethylene.
引用
收藏
页码:579 / 580
页数:2
相关论文
共 50 条
  • [1] Synthesis of a new ligand containing 1,7-diaza-12-crown-4 and the application in asymmetric cyclopropanation reaction
    Wang, CY
    Shang, ZC
    Mei, JH
    Yu, QS
    CHINESE CHEMICAL LETTERS, 2003, 14 (06) : 579 - 580
  • [2] Synthesis of substituted 1,7-diaza-12-crown-4 containing oxazolines and its application
    Wang, CY
    Shang, ZC
    Leng, TH
    Yu, QS
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2003, 23 (04) : 384 - 386
  • [3] Synthesis of a new chiral receptor containing 1,7-diaza-12-crown-4 and its application in chiral separation
    Wang, CY
    Shang, ZC
    Mei, JH
    Yu, QS
    SYNTHETIC COMMUNICATIONS, 2003, 33 (19) : 3381 - 3386
  • [4] Potential Li+ fluorescent probe: Synthesis of 1,7-diaza-12-crown-4 substituted coumarin derivative
    Stevens, Cameron L.
    Nutbrown, Diane L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [5] Lanthanide complexes based on a 1,7-diaza-12-crown-4 platform containing picolinate pendants:: A new structural entry for the design of magnetic resonance imaging contrast agents
    Mato-Iglesias, Marta
    Roca-Sabio, Adrian
    Palinkas, Zoltan
    Esteban-Gomez, David
    Platas-Iglesias, Carlos
    Toth, Eva
    de Blas, Andres
    Rodriguez-Blas, Teresa
    INORGANIC CHEMISTRY, 2008, 47 (17) : 7840 - 7851
  • [6] Determination of the Stoichiometry, Stability Constant of Complexes Formation and Thermodynamic Parameters between 15-Crown-5, 1, 4, 8, 11-Tetrathiacyclotetradecane and 1, 7-Diaza-12-crown-4 Macrocyclic Ligands in Acetonitrile - Methanol Binary Solvent Mixtures
    Kazemi, Malihe Samdi
    Shamshirgaran, Bita
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2016, 11 (05): : 3415 - 3424
  • [7] Stability, Water Exchange, and Anion Binding Studies on Lanthanide(III) Complexes with a Macrocyclic Ligand Based on 1,7-Diaza-12-crown-4: Extremely Fast Water Exchange on the Gd3+ Complex
    Palinkas, Zoltan
    Roca-Sabio, Adrian
    Mato-Iglesias, Marta
    Esteban-Gomez, David
    Platas-Iglesias, Carlos
    de Blas, Andres
    Rodriguez-Blas, Teresa
    Toth, Eva
    INORGANIC CHEMISTRY, 2009, 48 (18) : 8878 - 8889
  • [8] Eight-Coordinate Zn(II), Cd(II), and Pb(II) Complexes Based on a 1,7-Diaza-12-crown-4 Platform Endowed with a Remarkable Selectivity over Ca(II)
    Ferreiros-Martinez, Raquel
    Esteban-Gomez, David
    de Blas, Andres
    Platas-Iglesias, Carlos
    Rodriguez-Blas, Teresa
    INORGANIC CHEMISTRY, 2009, 48 (24) : 11821 - 11831
  • [9] Synthesis of a new chiral amino phosphine ligand and its application in the asymmetric allylic alkylation (AAA) reaction
    Feng, Jianqing
    Bohle, D. Scott
    Li, Chao-Jun
    TETRAHEDRON-ASYMMETRY, 2007, 18 (09) : 1043 - 1047
  • [10] New highly asymmetric henry reaction catalyzed by CuII and a C1-Symmetric aminopyridine ligand, and its application to the synthesis of miconazole
    Blay, Gonzalo
    Domingo, Luis R.
    Hernandez-Olmos, Victor
    Pedro, Jose R.
    CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (15) : 4725 - 4730