Synthesis of substituted 1,7-diaza-12-crown-4 containing oxazolines and its application

被引：0
|
作者：
Wang, CY [1 ]
Shang, ZC [1 ]
Leng, TH [1 ]
Yu, QS [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 23卷 / 04期
关键词：
1,7-diaza-12-crown-4; oxazoline; synthesis; asymmetric cyclopropanation;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
New bibracchiral lariat crown ethers 1a similar to 1c were synthesized by treatment of 1, 7-diaza-12-crown-4 with chiral oxazolines 2a similar to 2c. 2a similar to 2c were prepared from amino alcohols and triethyl orthochloroacetate. Cu ( 11) complexes of 1a similar to 1c were applied to the asymmetric cyclopropanation of 1, 1-diphenyl ethylene with alkyl diazoacetate.
引用
收藏
页码：384 / 386
页数：3
相关论文
共 11 条
  • [1] cis-Selective cyclopropanations using chiral 5,5-diaryl bis(oxazoline) catalysts
    Alexander, K
    Cook, S
    Gibson, CL
    [J]. TETRAHEDRON LETTERS, 2000, 41 (36) : 7135 - 7138
  • [2] Asymmetric cyclopropanation catalyzed by C2-symmetric bi(oxazolines)
    Boulch, R
    Scheurer, A
    Mosset, P
    Saalfrank, RW
    [J]. TETRAHEDRON LETTERS, 2000, 41 (07) : 1023 - 1026
  • [3] SYNTHESIS OF HOMOCHIRAL BIS(OXAZOLINYL) PYRIDINE TYPE LIGANDS FOR ASYMMETRIC CYCLOPROPANATION REACTIONS
    GUPTA, AD
    BHUNIYA, D
    SINGH, VK
    [J]. TETRAHEDRON, 1994, 50 (48) : 13725 - 13730
  • [4] New homochiral bis(oxazoline) ligands for asymmetric catalysis
    Hoarau, O
    AitHaddou, H
    Castro, M
    Balavoine, GGA
    [J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (22) : 3755 - 3764
  • [5] Synthesis of optically active 2-chloromethyl-2-oxazolines by the ortho-ester condensation method using triethyl orthochloroacetate
    Kamata, K
    Sato, H
    Takagi, E
    Agata, I
    Meyers, AI
    [J]. HETEROCYCLES, 1999, 51 (02) : 373 - 378
  • [6] A CONVENIENT REDUCTION OF AMINO-ACIDS AND THEIR DERIVATIVES
    MCKENNON, MJ
    MEYERS, AI
    DRAUZ, K
    SCHWARM, M
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (13): : 3568 - 3571
  • [7] The unique behavior of a chiral binaphthyl oxazoline in the presence of Cu(I) and its role as a chiral catalyst
    Meyers, AI
    Price, A
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (03): : 412 - 413
  • [8] NEW CHIRAL RUTHENIUM BIS(OXAZOLINYL)PYRIDINE CATALYST - EFFICIENT ASYMMETRIC CYCLOPROPANATION OF OLEFINS WITH DIAZOACETATES
    NISHIYAMA, H
    ITOH, Y
    MATSUMOTO, H
    PARK, SB
    ITOH, K
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (05) : 2223 - 2224
  • [9] SHENG HY, 1983, ACTA CHIM SINICA, V41, P1127
  • [10] CYCLOPROPANES .13. ABSOLUTE CONFIGURATION OF 1-METHYL-2,2-DIPHENYLCYCLOPROPANE
    WALBORSKY, HM
    PITT, CG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (24) : 4831 - &
12