Synthesis and Crystal Structure of 〔P（CH2Ph）Ph3〕〔PdWS4（S2CNC4H8）〕

被引：0

作者：

LONG De-Liang

YAN Duan-Chao

CHENG Wen-Dan

HUANG Jin-Shun(State Key Laboratory of Structural Chemistry

机构：

来源：

结构化学 | 1998年 / 02期

关键词：

synthesis; crystal structure; dithiocarbamate; palladium-tungsten-sulfur;

D O I：

10.14102/j.cnki.0254-5861.1998.02.017

中图分类号：

O627 [元素有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound, [P (CH2Ph) Ph3] [PdWS4(S2CNC4H8)], wassynthesized by ligand replacement reaction of Pd(S2CNC4H8)2 with (NH4)2WS4 in thepresence of [P(CH2Ph)Ph3]Cl in CH2Cl2 and characterized by X-ray diffraction analy-ses. Crystallographic data: triclinic, observed reflections with . The crys-tal contains discrete cations and anions. Palladium atom in the anion is coordinated by apyrrolidine-derived dithiocarbamate and a tetrathiotungstate. Both dithiocarbamate andtetrathiotungstate act as bidentate ligands through two sulfur atoms chelating palladiumatom. The Pd-W distance is 2- 847(1).

引用

页码：155 / 158

页数：4

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