Determination of the Absolute Configuration of Rohitukine

被引：0
|
作者：
Dong Hui YANG
机构：
来源：
ChineseChemicalLetters | 2003年 / 07期
关键词：
Dysoxylum binectariferum; absolute configuration; rohitukine;
D O I：
暂无
中图分类号：
O72 [X射线晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The absolute configuration of rohitukine, isolated from the stem-bark of Dysoxylum binectariferum, was determined to be 5,7-dihydroxy-2-methyl-8-[4-(3S, 4R-3-hydroxy-1-methyl) -piperidinyl]-4H-1-benzopyran-4-one by X-ray crystallographic analysis on the crystal of 4-bromobenzoyl derivatives of rohitukine. At the same time, the modified Mosher method was proved to be unsuitable for determining the absolute configuration of C-3 position in rohitukine.
引用
收藏
页码：720 / 723
页数：4
相关论文
共 50 条
  • [21] Synthesis and determination of the absolute configuration of Fudecalone
    Watanabe, H
    Yamaguchi, T
    Furuuchi, T
    Kido, M
    Bando, M
    Kitahara, T
    ARKIVOC, 2003, : 267 - 282
  • [22] A DETERMINATION METHOD OF ABSOLUTE-CONFIGURATION
    TODA, F
    MORI, K
    SATO, A
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (11) : 4167 - 4169
  • [23] Determination of the complete absolute configuration of petriellin A
    Aurelio, Luigi
    Brownlee, Robert T. C.
    Dang, Jason
    Hughes, Andrew B.
    Polya, Gideon M.
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2006, 59 (06) : 407 - 414
  • [24] DETERMINATION OF ABSOLUTE CONFIGURATION OF CIS 1,2-DIALKYLCYCLOPROPANES - APPLICATION TO DETERMINATION OF ABSOLUTE CONFIGURATION OF LACTOBACILLIC ACID
    TOCANNE, JF
    TETRAHEDRON, 1972, 28 (02) : 363 - &
  • [25] DETERMINATION OF THE ABSOLUTE CONFIGURATION OF ALPHA-QUARTZ
    DEVRIES, A
    NATURE, 1958, 181 (4617) : 1193 - 1193
  • [26] Total Synthesis of (+)-Perophoramidine and Determination of the Absolute Configuration
    Wu, Haoxing
    Xue, Fei
    Xiao, Xue
    Qin, Yong
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (40) : 14052 - 14054
  • [27] Total Synthesis and Determination of the Absolute Configuration of (-)-Dolabriferol
    Laclef, Sylvain
    Turks, Maris
    Vogel, Pierre
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (45) : 8525 - 8527
  • [28] Total Synthesis and Determination of the Absolute Configuration of (-)-Idesolide
    Yamakoshi, Hiroyuki
    Shibuya, Masatoshi
    Tomizawa, Masaki
    Osada, Yuji
    Kanoh, Naoki
    Iwabuchi, Yoshiharu
    ORGANIC LETTERS, 2010, 12 (05) : 980 - 983
  • [29] A NEW APPROACH TO THE DETERMINATION OF ABSOLUTE-CONFIGURATION
    JONES, W
    NATURE, 1982, 296 (5852) : 11 - 12
  • [30] Stereoselective Synthesis and Absolute Configuration Determination of Xylariolide A
    Manuel Botubol, Jose
    Macias-Sanchez, Antonio J.
    Collado, Isidro G.
    Hernandez-Galan, Rosario
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (12) : 2420 - 2427
12345