Controllable macrocyclic supramolecular assemblies in aqueous solution

被引：0

作者：

Yong Chen ^{[1
,2
]}

Feihe Huang ^{[3
]}

Zhan-Ting Li ^{[4
]}

Yu Liu ^{[1
,2
]}

机构：

[1] State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University

[2] Co-Innovation Center of Chemistry and Chemical Engineering (Tianjin)

[3] State Key Laboratory of Chemical Engineering, Center for Chemistry of High-Performance & Novel Materials, Department of Chemistry,Zhejiang University

[4] Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials and Collaborative Innovation Centre of Chemistry for Energy Materials (iChEM), Fudan University

来源：

Science China(Chemistry) | 2018年 / 61卷 / 08期

基金：

中国国家自然科学基金;

关键词：

macrocycle; supramolecular assembly; stimuli-responsive; aqueous solution;

D O I：

暂无

中图分类号：

O641.3 [分子间的相互作用、超分子化学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of macrocycles, including crown ethers, cyclodextrins, calixarenes, pillararenes and cucurbiturils, are well known to be able to associate various organic/inorganic/biological guest molecules and ions in their well-defined cyclic cavities to form stable host-guest complexes and supramolecular systems through the cooperative contributions of various non-covalent interactions.When one or more functional groups are attached to the cavity of macrocycles or guest molecules, enhanced and/or controlled host-guest associations may take place, leading to not only improved host-guest binding abilities but also fascinating properties.In this review, some representative contributions in the construction of controllable macrocyclic supramolecular assemblies in aqueous solution are presented with an emphasis on the stimuli-responsive control manner and wide applications of this property.

引用

页码：979 / 992

页数：14

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